Process on Metal-Orgainc Frameworks for Heterogeneous Catalysis
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摘要: 相比传统的多孔碳和无机沸石材料，金属-有机骨架（MOFs）具有制备方便、易于修饰、高孔隙率、大比表面积、框架规模大小可调等优点，由于它们在气体存储、吸附分离、多相催化、磁性的潜在应用而受到广泛关注。本文首先介绍了MOFs作为多相催化剂所具有的独特特点；其次评估MOFs作为催化剂的潜力，重点从MOFs的结构要素出发总结了MOFs作为多相催化剂的应用现状。最后讨论了MOFs作为多相催化剂需要重视的问题，为定向合成此类材料在催化方面的应用提供有意义的实验基础和理论价值。
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关键词:
- 多相催化
Abstract: Compared with the traditional porous carbons and inorganic zeolites, metal-organic frameworks (MOFs) have the advantages of convenient preparation, easy modification, high porosity, large specific surface area and adjustable pore size, and have attracted extensive attention recently due to their potential applications in gas storage, adsorption and separation, heterogeneous catalysis, as well as magnetism. In this review, the unique advantages of MOFs as heterogeneous catalysis are firstly introduced. Then, the potential of MOFs as catalysts will be evaluated and the application status based on their structural element will be particularly summarized. Finally, we discuss the problems needed to be focused on, and provide meaningful experimental basis and theoretical value for the directional synthesis of these materials in catalysis.-
Keywords:
- heterogeneous catalysis
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DOI: 10.1039/B718371B [6]Schlichte K, Kratzke T, Kaskel S.Improved synthesis,thermal stability and catalytic properties of the metal-organic framework compound Cu3(BTC)2[J].Microporous and Mesoporous Materials, 2004, 73(1-2):81-88 [7]Dinca M, Dailly A, Liu Y, et al.Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites[J].Journal of the American Chemistry Society, 2006, 128(51):16876-16883 [8]Wu P, He C, Wang J, et al.Photoactive chiral metal-organic frameworks for light-driven asymmetric alpha-alkylation of aldehydes[J].Journal of the American Chemistry Society, 2012, 134(36):14991-14999 [9] Banerjee M, Das S, Yoon M, et al.Postsynthetic modification switches an achiral framework to catalytically active homochiral metal-organic porous materials [J]. Journal of the American Chemistry Society, 2009, 131: 7524-7525. 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