微纤化纤维素基复合膜的质子交换性能

Proton Exchange Performance of Microfibrillar Cellulose/Lignin Sulfonate Composite Membrane

  • 摘要: 提出了微纤化纤维素“微溶-焊接”策略,采用尿素/NaOH溶液对微纤化纤维素进行微溶处理并使其在凝固浴中重新凝固析出的方法,制备了微纤化纤维素/木质素磺酸盐复合膜,研究其力学性能、溶胀性能及质子传输性能等。结果表明:复合膜在完全水合状态下的力学强度为3.7±0.2 MPa,杨氏模量为58.6±3.9 MPa,吸水率(质量分数)为(82±1)%,平面溶胀率为(13±2)%,复合膜在80 ℃下的质子传导率为0.056 S/cm,甲醇渗透系数为2.86×10-6 cm2/s。该研究提出的“微溶-焊接”策略,有望在纤维素功能膜领域得到应用。

     

    Abstract: The article proposed a "micro-dissolution-welding" strategy tailored for microfibrillar cellulose (MFC). MFC was "micro-dissolved" in Urea/NaOH solution and the MFC fibers were "welded" together in coagulation bath, resulting in the formation of an MFC/lignosulfonate composite membrane. The mechanical properties, swelling behavior, and proton transport properties of this composite membrane in moisture environment were investigated. The mechanical strength and the the young's modulus of the resultant MFC/lignosulfonate composite membrane are 3.7±0.2 MPa and 58.6±3.9 MPa, respectively. The water absorption and planer swelling ratio of the composite membrane in water are (82±1)% and (13±2)%, respectively. The proton conductivity of the composite membrane at 80 ℃ reaches 0.056 S/cm, and its methanol permeability coefficient is 2.86×10-6 cm2/s. The proposed "micro-dissolution-welding" strategy has promising applications in the field of cellulose-based functional membranes.

     

/

返回文章
返回