Abstract:
The ITO/ZnO/interface layer (IFL)/MAPbI
3/Sprio-OMeTAD/Au structure of Perovskite Solar Cells (PSCs) and the electron transport layer (ETL)/absorber interface engineering are studied based on the wxAMPS solar cell numerical simulation software micro-platform. The results show that the performance of PSCs is almost unchanged when the defect density of the interface layer is lower than 10
14 cm
-3, and when the defect density is higher than 10
14 cm
-3, the performance of PSCs declines sharply. When the affinity difference(Δ
χ) between the interface layer and the absorber layer is within the range of -0.7~-0.1 eV, the parameters of PSCs increase with the increase of Δ
χ; when Δ
χ is within the range of -0.1~0.5 eV, the solar cell performance shows a gentle increase. When Δ
χ is greater than 0.5 eV, the short-circuit current (
JSC) of the solar cell shows a gentle increase while the open circuit voltage (
VOC), fill factor (FF) and photovoltaic conversion efficiency (PCE) decrease rapidly. When the band gap
Eg increases within 0.9~1.4 eV, the
VOC, FF and PCE of PSCs increase. When the band gap
Eg is greater than 1.4 eV, the performance parameters of PSCs remain unchanged basically.