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WANG Xi, XIAO Zijun, WANG Jing, LI Laisheng. Hydrothermal Preparation of Bi2WO6 and Its Photocatalytic Degradation of Clofibric Acid[J]. Journal of South China Normal University (Natural Science Edition), 2023, 55(5): 39-46. DOI: 10.6054/j.jscnun.2023061
Citation: WANG Xi, XIAO Zijun, WANG Jing, LI Laisheng. Hydrothermal Preparation of Bi2WO6 and Its Photocatalytic Degradation of Clofibric Acid[J]. Journal of South China Normal University (Natural Science Edition), 2023, 55(5): 39-46. DOI: 10.6054/j.jscnun.2023061

Hydrothermal Preparation of Bi2WO6 and Its Photocatalytic Degradation of Clofibric Acid

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  • Received Date: October 21, 2022
  • Available Online: January 21, 2024
  • Bi2WO6 with visible light response were prepared by a one-step hydrothermal method. The materials were characterized and analyzed by SEM, TEM, XRD and UV-Vis DRS. Reactive substances were characterized by ESR technique. Photocatalytic performance was tested with Clofibric Acid as the target pollutant, and the effects of pollutant concentration, catalyst dosage, current strength, solution pH, anion and Humic Acid presence on the photocatalytic performance were investigated. The experiments showed that the Bi2WO6 material had good catalytic effect on Clofibric Acid under visible light and achieved the best degradation under the conditions of pollutant concentration of 10 mg/L, catalyst dosage of 60 mg(0.6 g/L), current intensity of 20 A, initial solution pH of 5.0 and without Humic Acid. h+ and ·OH were the main active oxidizing substances of the reaction, and the photodegradation rate of the material decreased only less than 2% after five cycles.

  • [1]
    WANG J, CHU L. Irradiation treatment of pharmaceutical and personal care products (PPCPs) in water and wastewater: an overview[J]. Radiation Physics and Chemistry(Natural Science Edition), 2016, 125: 56-64.
    [2]
    LI W, SHI Y, GAO L, et al. Occurrence of antibiotics in water, sediments, aquatic plants, and animals from Baiyangdian Lake in North China[J]. Chemosphere(Natural Science Edition), 2012, 89(11): 1307-1315.
    [3]
    BURLACU I, FAVIER L, MATEI E, et al. Photocatalytic degradation of a refractory water pollutant using nanosized catalysts[J]. Journal of Environmental Protection and Ecology(Science Edition), 2020, 21(2): 571-578.
    [4]
    LI W, LU S, QIU Z, et al. Photocatalysis of clofibric acid under solar light in summer and winter seasons[J]. Industrial & Engineering Chemistry Research(Science Edition), 2011, 50(9): 5384-5393.
    [5]
    张帆, 柴凤兰, 单国庆, 等. 焙烧温度对钨酸铋光催化降解四环素性能的影响[J]. 化学研究与应用(自然科学版), 2021, 33(12): 2413-2419.

    ZHANG F, CHAI F L, SHAN G Q, et al. Effect of roasting temperature on the performance of bismuth tungstate photocatalytic degradation of tetracycline[J]. Chemical Research and Applications(Natural Science Edition), 2021, 33(12): 2413-2419.
    [6]
    刘秀, 王磊, 刘婷婷, 等. 钨酸铋光催化降解萘普生效果及其机理[J]. 环境工程学报(自然科学版), 2020, 14(10): 2643-2653.

    LIU X, WANG L, LIU T T, et al. Effect of bismuth tungstate photocatalytic degradation of naproxen and its mechanism[J]. Journal of Environmental Engineering(Natural Science Edition), 2020, 14(10): 2643-2653.
    [7]
    王石, 张行天, 叶希章, 等. 碳纤维布上负载钨酸铋的光催化性能[J]. 工业催化(自然科学版), 2022, 30(2): 35-40.

    WNAG S, ZHANG X T, YE X Z, et al. Photocatalytic performance of bismuth tungstate loaded on carbon fiber cloth[J]. Industrial Catalysis(Natural Science Edition), 2022, 30(2): 35-40.
    [8]
    蔡启祥, 赵丹, 曹瑞芳, 等. Pt/石墨烯/花球状钨酸铋复合光催化剂的制备及其在降解有机染料中的应用[J]. 赤峰学院学报(自然科学版), 2021, 37(8): 12-18.

    CAI Q X, ZHAO D, CAO R F, et al. Preparation of Pt/graphene/flower spherical bismuth tungstate composite photocatalyst and its application in degrading organic dyes[J]. Journal of Chifeng College(Natural Science Edition), 2021, 37(8): 12-18.
    [9]
    HUANG H, WANG S, TIAN N, et al. A one-step hydrothermal preparation strategy for layered BiIO4/Bi2WO6 heterojunctions with enhanced visible light photocatalytic activities[J]. RSC Advances, 2014, 4(11): 5561-5567. doi: 10.1039/c3ra45891a
    [10]
    LI Z, YANG S, ZHOU J, et al. Novel mesoporous g-C3N4 and BiPO4 nanorods hybrid architectures and their enhanced visible-light-driven photocatalytic performances[J]. Chemical Engineering Journal, 2014, 241: 344-351. doi: 10.1016/j.cej.2013.10.076
    [11]
    YUE L, WANG S, SHAN G, et al. Novel MWNTs-Bi2WO6 composites with enhanced simulated solar photoactivity toward adsorbed and free tetracycline in water[J]. Applied Catalysis B: Environmental, 2015, 176: 11-19.
    [12]
    HUANG H W, LIU K, CHEN K, et al. Ce and F comodification on the crystal structure and enhanced photocatalytic activity of Bi2WO6 photocatalyst under visible light irradiation[J]. The Journal of Physical Chemistry C, 2014, 118(26): 14379-14387.
    [13]
    QIAN X, YUE D, TIAN Z, et al. Carbon quantum dots decorated Bi2WO6 nanocomposite with enhanced photocatalytic oxidation activity for VOCs[J]. Applied Catalysis B: Environmental, 2016, 193: 16-21.
    [14]
    LI Z, LUO M, LI B, et al. 3-D hierarchical micro/nano-structures of porous Bi2WO6: controlled hydrothermal synthesis and enhanced photocatalytic performances[J]. Microporous and Mesoporous Materials, 2020, 313: 110-830.
    [15]
    CHEN D Y, LI B L, PU Q M, et al. Preparation of Ag-AgVO3/g-C3N4 composite photo-catalyst and degradation characteristics of antibiotics[J]. Journal of Hazardous Materials, 2019, 373: 303-312.
    [16]
    郭佑罗, 关小红, 高乃云, 等. 紫外/过硫酸盐工艺降解水中氯贝酸的研究[J]. 中国环境科学, 2016, 36(7): 2014-2019.

    GUO Y L, GUAN X H, GAO N Y, et al. Study on the degradation of clofibrate in water by UV/Persulfate process[J]. China Environmental Science, 2016, 36(7): 2014-2019.
    [17]
    GREBEI J E, PIGNATELLO J I, MITCH W A. Effect of halide ions and carbonates on organic contaminant degradation by hydroxyl radical-based advanced oxidation processes in saline waters[J]. Environmental Science & Technology, 2010, 44(17): 6822-6828.
    [18]
    LIAO C H, GUROL M D. Chemical oxidation by photolytic decomposition of hydrogen peroxide[J]. Environmental Science & Technology, 1995, 29(12): 3007-3014.
    [19]
    LATIFOGLU A, GUROL M. The effect of humic acids on nitrobenzene oxidation by ozonation and O3/UV processes[J]. Science, 2003, 37(8): 1879-1889.
    [20]
    LIRA E, WENDT S, HUO P, et al. The importance of bulk Ti3+ defects in the oxygen chemistry on titania surfaces[J]. Journal of the American Chemical Society(Natural Science Edition), 2011, 133(17): 6529-6532.

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