The Highly Selective and Sensitive Carbazole Derivative F<sup>-</sup> Fluorescence-enhanced Probe

MA Lijun; XU Weishao; LIU Xin; LU Pinting; XU Jinsong; FENG Ruihong

doi:10.6054/j.jscnun.2022055

Journal of South China Normal University (Natural Science Edition) > 2022 > 54(4): 32-39. > DOI: 10.6054/j.jscnun.2022055

MA Lijun, XU Weishao, LIU Xin, LU Pinting, XU Jinsong, FENG Ruihong. The Highly Selective and Sensitive Carbazole Derivative F^- Fluorescence-enhanced Probe[J]. Journal of South China Normal University (Natural Science Edition), 2022, 54(4): 32-39. DOI: 10.6054/j.jscnun.2022055

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The Highly Selective and Sensitive Carbazole Derivative F^- Fluorescence-enhanced Probe

School of Chemistry, South China Normal University, Guangzhou 510006, China

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Received Date: September 29, 2021
Available Online: September 21, 2022

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Abstract

Abstract

A carbazole derivative (HCTC) containing siloxy groups was synthesized using 4-hydroxycarbazole as the raw material. The structure was characterized with ¹H NMR and MS, and the F^- detection performance of the probe was studied. The results showed that HCTC could take advantage of the nucleophilicity of F^- to specifically attack the silicon-oxygen bond, showing the characteristics of a chemically reactive fluorescent probe towards F^-. Fluorescence test results showed that when F^- was added, a new fluorescence emission peak appeared in the probe solution at the wavelength of 433 nm, accompanied by a slight red shift, while the addition of other common anions could not cause fluorescence enhancement. In addition, the detection limit of F^- by HCTC was relatively low (0.21 μmol/L). Finally, the HCTC probe was prepared into a fluorescent test paper, which could detect F^- in an aqueous solution containing a small amount of acetonitrile. HCTC can be a fluorescence-enhanced probe with high selectivity and sensitivity.
- 4-hydroxycarbazole,
- fluorescent probe,
- F^-,
- fluorescent test paper

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References

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The Highly Selective and Sensitive Carbazole Derivative F^- Fluorescence-enhanced Probe