The Preparation of LaAl0.5Ni0.5O3 Perovskite and Its Catalytic Performance in Methane Dry Reforming

MA Yujie; GE Yizhao; SU Peng; WANG Zijun; LI Yongsheng

doi:10.6054/j.jscnun.2022045

Journal of South China Normal University (Natural Science Edition) > 2022 > 54(3): 53-61. > DOI: 10.6054/j.jscnun.2022045

MA Yujie, GE Yizhao, SU Peng, WANG Zijun, LI Yongsheng. The Preparation of LaAl_0.5Ni_0.5O₃ Perovskite and Its Catalytic Performance in Methane Dry Reforming[J]. Journal of South China Normal University (Natural Science Edition), 2022, 54(3): 53-61. DOI: 10.6054/j.jscnun.2022045

Citation:

PDF (2471 KB)

The Preparation of LaAl_0.5Ni_0.5O₃ Perovskite and Its Catalytic Performance in Methane Dry Reforming

1.
School of Chemistry and Chemical Engineering, Shihezi University/The Xinjiang Production and Construction Corps Key Laboratory for Green Processing of Chemistry and Chemical Engineering, Shihezi 832003, China
2.
School of Materials Science and Engineering, East China University of Science and Technology/MOE Key Laboratory for Ultrafine Materials, Shanghai 200237, China

More Information

Received Date: November 30, 2021
Available Online: July 28, 2022

Graphical Abstract

Abstract

Abstract

The hard template method was used to prepare the mesoporous LaAl_1-xAl_xO₃ perovskite catalyst with a large surface area, which was used for carbon-neutral methane dry reforming for reaction activity test at different temperatures. With scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffractometer (XRD), N₂ adsorption and desorption (BET), H₂ temperature programmed reduction (H₂-TPR), thermogravimetric analysis (TGA) and other methods, the as-prepared catalyst was characterized. The results showed that the LaAl_0.5Ni_0.5O₃ catalyst exhibited the most excellent activity and stability during the reaction, the initial activity of CH₄ and CO₂ in the LaAl_0.5Ni_0.5O₃ catalyst reached 69.8% and 81.5% respectively under the conditions of reaction temperature of 750 ℃ and space velocity GHSV=36 000 mL/(g·h). And the CH₄ and CO₂ activity of the LaAl_0.5Ni_0.5O₃ catalyst reduced by 2.7% and 3.3% respectively after the 25 h stability test. The reason was that the LaAl_0.5Ni_0.5O₃ catalyst obtained more Ni active sites than the LaAl_0.7Ni_0.3O₃ catalyst and the LaAl_0.5Ni_0.5O₃ catalyst had more favorable anti-sintering and anti-carbon deposition ability than the LaAl_0.3Ni_0.7O₃ catalyst.
- hard template method,
- carbon neutrality,
- Ni-based perovskite,
- methane dry reforming

FullText(HTML)

References (30)

References

[1]	李风雷, 尹璐, 赵吉, 等. 以能源转型推进"碳中和"的北欧经验借鉴与中国方案初探[J]. 可再生能源, 2021, 39(10): 1308-1313. doi: 10.3969/j.issn.1671-5292.2021.10.005 LI F L, YIN L, ZHAO J, et al. The nordic experiences and Chinese choices for improving "Carbon Neutrality" by energy transition[J]. Renewable Energy Resources, 2021, 39(10): 1308-1313. doi: 10.3969/j.issn.1671-5292.2021.10.005
[2]	卢金凯, 张梦, 李斌, 等. 功能化氧化石墨烯催化CO₂的化学固定[J]. 华南师范大学学报(自然科学版), 2021, 53(3): 35-42. https://www.cnki.com.cn/Article/CJFDTOTAL-HNSF202103006.htm LU J K, ZHANG M, LI B, et al. Chemical fixation of CO₂ catalyzed by functionalized graphene oxide[J]. Journal of South China Normal University (Natural Science Edition), 2021, 53(3): 35-42. https://www.cnki.com.cn/Article/CJFDTOTAL-HNSF202103006.htm
[3]	SINGH R, DHIR A, MOHAPATRA S, et al. Dry reforming of methane using various catalysts in the process: review[J]. Biomass Convers and Biorefinery, 2020, 10(2): 567-587. doi: 10.1007/s13399-019-00417-1
[4]	MOREIRA T, FILHO J, CARVALHO Y, et al. Highly stable low noble metal content rhodium-based catalyst for the dry reforming of methane[J]. Fuel, 2021, 287: 119536/1-10. https://www.sciencedirect.com/science/article/pii/S0016236120325321
[5]	ANIL C, MODAK J M, MADRAS G. Syngas production via CO₂ reforming of methane over noble metal (Ru, Pt, and Pd) doped LaAlO₃ perovskite catalyst[J]. Molecular Catalysis, 2019, 484: 110805/1-11. https://www.sciencedirect.com/science/article/pii/S1226086X13002190
[6]	PAN C, GUO Z L, DAI H, et al. Anti-sintering mesoporous Ni-Pd bimetallic catalysts for hydrogen production via dry reforming of methane[J]. International Journal of Hydrogen Energy, 2020, 45(32): 16133-16143. doi: 10.1016/j.ijhydene.2020.04.066
[7]	QIN Z Z, CHEN J, XIE X L, et al. CO₂ reforming of CH₄ to syngas over nickel-based catalysts[J]. Environmental Chemistry Letters, 2020, 18(4): 997-1017. doi: 10.1007/s10311-020-00996-w
[8]	BHATTAR S, ABEDIN M A, KANITKAR S, et al. A review on dry reforming of methane over perovskite derived catalysts[J]. Catalysis Today, 2021, 365: 2-23. doi: 10.1016/j.cattod.2020.10.041
[9]	RUAN Y Z, ZHAO Y F, LU Y, et al. Mesoporous LaAl_0.25Ni_0.75O₃ perovskite catalyst using SBA-15 as templating agent for methane dry reforming[J]. Microporous and Mesoporous Materials, 2020, 303: 110278/1-43.
[10]	RIVAS I, ALVAREZ J, PIETRI E, et al. Perovskite-type oxides in methane dry reforming: effect of their incorporation into a mesoporous SBA-15 silica-host[J]. Catalysis Today, 2009, 149 (3): 388-393. https://www.sciencedirect.com/science/article/pii/S0920586109003459
[11]	NAIR M M, KALIAGUINE S, KLEITZ F, et al. Nanocast LaNiO₃ perovskites as precursors for the preparation of coke-resistant dry reforming catalysts[J]. ACS Catalysis, 2014, 4 (11): 3837-3846. doi: 10.1021/cs500918c
[12]	SONG J W, DUAN X H, ZHANG W W. Methane dry reforming over mesoporous La₂O₃ supported Ni catalyst for syngas production[J]. Microporous and Mesoporous Materials, 2021, 310: 110587/1-8.
[13]	BAI X L, XIE G M, GUO Y, et al. A highly active Ni catalyst supported on Mg-substituted LaAlO₃ for carbon dioxide reforming of methane[J]. Catalysis Today, 2021, 368: 78-85. doi: 10.1016/j.cattod.2019.12.033
[14]	LEE G, KIM I, YANG I, et al. Effects of the preparation method on the crystallinity and catalytic activity of LaAlO₃ perovskites for oxidative coupling of methane[J]. Applied Surface Science, 2018, 429: 55-61. doi: 10.1016/j.apsusc.2017.08.092
[15]	WANG Z J, WANG H, LIU Y, et al. La_1-xCa_xFe_1-xCo_xO₃, a stable catalyst for oxidative steam reforming of ethanol to produce hydrogen[J]. RSC Advances, 2013, 3(25): 10027-10036. doi: 10.1039/c3ra23487h
[16]	WANG N, YU X P, WANG Y, et al. A comparison study on methane dry reforming with carbon dioxide over LaNiO₃ perovskite catalysts supported on mesoporous SBA-15, MCM-41 and silica carrier[J]. Catalysis Today, 2013, 212: 98-107. doi: 10.1016/j.cattod.2012.07.022
[17]	LU Y, GUO D, RUAN Y Z, et al. Facile one-pot synthesis of Ni@HSS as a novel yolk-shell structure catalyst for dry reforming of methane[J]. Journal of CO₂ Utilization, 2018, 24: 190-199. doi: 10.1016/j.jcou.2018.01.003
[18]	SAGAR T V, PADMAKAR D, LINGAIAH N, et al. Syngas production by CO₂ reforming of methane on LaNi_xAl_1-xO₃ perovskite catalysts: influence of method of preparation[J]. Journal of Chemical Sciences, 2017, 129 (11): 1787-1794. doi: 10.1007/s12039-017-1359-2
[19]	WANG N, SHEN K, HUANG L, et al. Facile route for synthesizing ordered mesoporous Ni-Ce-Al oxide materials and their catalytic performance for methane dry reforming to hydrogen and syngas[J]. ACS Catalysis, 2013, 3 (7): 1638-1651. doi: 10.1021/cs4003113
[20]	TAHERIAN Z, KHATAEE A, OROOJI Y. Nickel-based nanocatalysts promoted over MgO-modified SBA-16 for dry reforming of methane for syngas production: impact of support and promoters[J]. Journal of the Energy Institute, 2021, 97, 100-108. doi: 10.1016/j.joei.2021.04.005
[21]	CHEN C F, MENG Z J, WANG Z J. Large specific surface area macroporous nanocast LaFe_1-xNi_xO₃: a stable catalyst for catalytic methane dry reforming[J]. Journal of Chemistry, 2019, 2019: 1-9. https://www.hindawi.com/journals/jchem/2019/7851416/
[22]	Li Z W, KAWI S. Multi-Ni@Ni phyllosilicate hollow sphere for CO₂ reforming of CH₄: influence of Ni precursors on structure, sintering, and carbon resistance[J]. Catalysis Science & Technology, 2018, 8(7): 1915-1922. https://pubs.rsc.org/en/content/articlelanding/2018/cy/c8cy00024g#!
[23]	ZHANG Q, SUN M, NING P, et al. Effect of thermal induction temperature on re-dispersion behavior of Ni nanoparticles over Ni/SBA-15 for dry reforming of methane[J]. Applied Surface Science, 2019, 469: 368-377. doi: 10.1016/j.apsusc.2018.10.222
[24]	CHEN X, YIN L, LONG K, et al. The reconstruction of Ni particles on SBA-15 by thermal activation for dry reforming of methane with excellent resistant to carbon deposition[J]. Journal of the Energy Institute, 2020, 93(6): 2255-2263. doi: 10.1016/j.joei.2020.06.008
[25]	WANG H Q, DONG X L, ZHAO T T, et al. Dry reforming of methane over bimetallic Ni-Co catalyst prepared from La(Co_xNi_1-x)_0.5Fe_0.5O₃ perovskite precursor: catalytic activity and coking resistance[J]. Applied Catalysis B: Environmental, 2019, 245: 302-313. doi: 10.1016/j.apcatb.2018.12.072
[26]	WANG M, ZHAO T T, DONG X L, et al. Effects of Ce substitution at the A-site of LaNi_0.5Fe_0.5O₃ perovskite on the enhanced catalytic activity for dry reforming of methane[J]. Applied Catalysis B: Environmental, 2018, 224: 214-221. doi: 10.1016/j.apcatb.2017.10.022
[27]	JAFARBEGLOO M, TARLANI A, MESBATH W A, et al. One-pot synthesis of NiO-MgO nanocatalysts for CO₂ reforming of methane: the influence of active metal content on catalytic performance[J]. Journal of Natural Gas Science and Engineering, 2015, 27: 1165-1173. doi: 10.1016/j.jngse.2015.09.065
[28]	DAI H, YU P X, LIU H S, et al. Ni-Based catalysts supported on natural clay of attapulgite applied in the dry reforming of methane reaction[J]. New Journal of Chemistry, 2020, 44 (37): 16101-16109. doi: 10.1039/D0NJ03069D
[29]	LI L, ZHANG L M, SHI X F, et al. Carbon dioxide reforming of methane over nickel catalysts supported on mesoporous MgO[J]. Journal of Porous Materials, 2014, 21(2): 217-224. doi: 10.1007/s10934-013-9766-3
[30]	ZHANG Q L, WANG J, NING P, et al. Dry reforming of methane over Ni/SBA-15 catalysts prepared by homogeneous precipitation method[J]. Korean Journal of Chemical Engineering, 2017, 34 (11): 2823-2831. doi: 10.1007/s11814-017-0182-2

Cited By

Cited by

Periodical cited type(6)

1.	方艳林，王升帅，张伟，张妮，谢璇，张厚勇. 基于PEMS的非四机械尾气碳排放特征探析. 环境监控与预警. 2025(01): 98-102 .
2.	吴雨涟，杨洁，邵智娟，沈春其，裴程伟，秦龙飞，郑嘉兴，徐婷婷，阚诗烨，宋程璐，崔璀. 苏州市机动车排放清单及特征研究. 环境科学学报. 2024(09): 129-139 .
3.	陈佳昊，项雅静. 基于拥堵系数的上海市道路高分辨率碳排放时空分配方法研究. 环境科学与管理. 2024(11): 16-21 .
4.	石文哲，王峰，付合英，李忠飞，王亮，于海洋，唐忠锋. 基于全生命周期法的矿用柴油重卡碳核算. 环境工程学报. 2023(06): 1907-1914 .
5.	菅月诚，彭娜娜，高艳珊，王强. “双碳”背景下细颗粒物和臭氧污染研究进展. 能源环境保护. 2023(05): 190-200 .
6.	代洪娜，曾煜磊，施庆利，孙婷. 碳达峰与碳中和背景下省域高速公路网碳排放精细化测算方法. 华南师范大学学报(自然科学版). 2023(04): 1-13 .

Other cited types(6)

Get Citation

PDF

XML

Article views (887) PDF downloads (47) Cited by(12)

Turn off MathJax

Article Contents

Abstract

References

The Preparation of LaAl0.5Ni0.5O3 Perovskite and Its Catalytic Performance in Methane Dry Reforming

Abstract

References

Cited by

Periodical cited type(6)

Other cited types(6)

Catalog

Export File

Citation

Format

Content

The Preparation of LaAl_0.5Ni_0.5O₃ Perovskite and Its Catalytic Performance in Methane Dry Reforming