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LU Xueyi, WANG Ziling, CAI Mohang, LU Xia. The Design of High-performance Ruthenium Oxide Catalyst for Electrocatalytic Oxygen Evolution Reaction[J]. Journal of South China Normal University (Natural Science Edition), 2022, 54(3): 1-7. DOI: 10.6054/j.jscnun.2022036
Citation: LU Xueyi, WANG Ziling, CAI Mohang, LU Xia. The Design of High-performance Ruthenium Oxide Catalyst for Electrocatalytic Oxygen Evolution Reaction[J]. Journal of South China Normal University (Natural Science Edition), 2022, 54(3): 1-7. DOI: 10.6054/j.jscnun.2022036
shu

The Design of High-performance Ruthenium Oxide Catalyst for Electrocatalytic Oxygen Evolution Reaction

  • School of Materials, Sun Yat-sen University, Shenzhen 518107, China

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  • Received Date: March 27, 2022
  • Available Online: July 28, 2022
    Graphical Abstract
    • Abstract
  • One kind of HRu4O8 microrods were fabricated with solid-state calcination and the proton exchange method. The morphology and crystal structure of HRu4O8 microrods were characterized with X-ray diffraction, transmission electron microscopy, scanning electron microscopy, X-ray photoelectron spectroscopy and so on. The catalytic activity of HRu4O8 was evaluated with the linear scanning voltammetry, cyclic voltammetry, Tafel plot, chronopotentiometry and other electrochemical methods. The results showed that the preparation of HRu4O8 with the RuO2 nanoparticle precursor resulted in a significant increase of the electrochemical active surface area. HRu4O8 exhibited excellent electrocatalytic activity towards OER with an overpotential of only 208 mV at 10 mA/cm2, lower than that of RuO2 nanoparticles(276 mV). Moreover, HRu4O8 also presented outstanding stability for 10 h without apparent degradation. Such work sheds light on new perspectives for designing highly active electrocatalyst of water splitting.
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    • References (39)
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