A Bimetallic Oxide ZnMnO<sub>3</sub> as a High-performance Long-cycle Cathode for Zinc Ion Batteries

ZHUANG Qiangqiang; WAN Baofeng; WU Baozhu; WANG Haoli; WU Xikai

doi:10.6054/j.jscnun.2022005

Journal of South China Normal University (Natural Science Edition) > 2022 > 54(1): 30-35. > DOI: 10.6054/j.jscnun.2022005

ZHUANG Qiangqiang, WAN Baofeng, WU Baozhu, WANG Haoli, WU Xikai. A Bimetallic Oxide ZnMnO₃ as a High-performance Long-cycle Cathode for Zinc Ion Batteries[J]. Journal of South China Normal University (Natural Science Edition), 2022, 54(1): 30-35. DOI: 10.6054/j.jscnun.2022005

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A Bimetallic Oxide ZnMnO₃ as a High-performance Long-cycle Cathode for Zinc Ion Batteries

Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power/School of Environment and Chemical Engineering, Shanghai Electric Power University, Shanghai 200090, China

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Received Date: June 03, 2021
Available Online: March 13, 2022

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Abstract

Abstract

A bimetallic oxide (ZnMnO₃) is synthesized with the sol-gel method and used as the cathode for zinc ion batteries for the first time. Electrochemical tests show that the ZnMnO₃ exhibits a high specific discharge capacity (175 mA·h/g at 300 mA/g). At a current density of 1 000 mA/g, the specific discharge capacity is still 134 mA ·h/g. Compared with monometallic oxides, the material exhibits more excellent cycling stability and better rate performance. The ex-situ scanning electron microscope (SEM) characterization of the electrode surface morphology shows that the morphology of ZnMnO₃ can be well maintained during the cycling process so that it can have stable long-cycle performance. According to the results of ex-situ X-ray diffraction (XRD) analysis, the zinc storage mechanism of ZnMnO₃ is the insertion and extraction reaction.
- aqueous zinc ion battery,
- cathode material,
- bimetallic oxide,
- nanometer materials

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A Bimetallic Oxide ZnMnO3 as a High-performance Long-cycle Cathode for Zinc Ion Batteries

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A Bimetallic Oxide ZnMnO₃ as a High-performance Long-cycle Cathode for Zinc Ion Batteries