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JIANG Zhaowen, ZHENG Panfei, ZHENG Jilong, FENG Shuyun, TANG Shanfa, JIN Lijun. The Synthesis and Performance of Sulfonate Gemini Surfactant[J]. Journal of South China Normal University (Natural Science Edition), 2021, 53(5): 23-29. DOI: 10.6054/j.jscnun.2021071
Citation: JIANG Zhaowen, ZHENG Panfei, ZHENG Jilong, FENG Shuyun, TANG Shanfa, JIN Lijun. The Synthesis and Performance of Sulfonate Gemini Surfactant[J]. Journal of South China Normal University (Natural Science Edition), 2021, 53(5): 23-29. DOI: 10.6054/j.jscnun.2021071
shu

The Synthesis and Performance of Sulfonate Gemini Surfactant

  • 1.

    College of Petroleum Engineering, Yangtze University//Hubei Cooperative Innovation Center of Unconventional Oil and Gas, Wuhan 430100, China

  • 2.

    College of Petroleum Engineering, China University of Petroleum, Beijing 102249, China

  • 3.

    CNOOC Energy Technology and Services Limited, Tianjin 300452, China

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  • Received Date: October 30, 2020
  • Available Online: November 10, 2021
    Graphical Abstract
    • Abstract
  • Using sodium 2-chloroethyl sulfonate, 1, 3-propanediamine, epichlorohydrin, etc. as raw materials, a sulfonate-type anionic gemini surfactant was synthesized through substitution and ring-opening reactions, N, N-bis(3-chloro-2-hydroxypropane-N-hexadecyl secondary amine) propane diamine sodium diethyl sulfonate (GAS-316). The synthesis conditions of GAS-316 were optimized by controlling the variables; the structure of GAS-316 was characterized with FT-IR and 1HNMR, and its surface/interface properties were evaluated. The results showed that GAS-316 had excellent surface activity, its critical micelle concentration (CCMC) being 0.27×10-3 mol/L and its surface tension γCMC being 19.64 mN/m. At 45 ℃, the GAS-316 solution with a mass fraction of 0.5% could reduce the oil-water interfacial tension to 5.25×10-2 mN/m (low interfacial tension level) in 20 min, which had good interfacial activity.
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    • References (20)
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