Chemical Fixation of CO<sub>2</sub> Catalyzed by Functionalized Graphene Oxide

LU Jinkai; ZHANG Meng; LI Bin; DONG Lihui; FAN Minguang

doi:10.6054/j.jscnun.2021041

Journal of South China Normal University (Natural Science Edition) > 2021 > 53(3): 35-42. > DOI: 10.6054/j.jscnun.2021041

LU Jinkai, ZHANG Meng, LI Bin, DONG Lihui, FAN Minguang. Chemical Fixation of CO₂ Catalyzed by Functionalized Graphene Oxide[J]. Journal of South China Normal University (Natural Science Edition), 2021, 53(3): 35-42. DOI: 10.6054/j.jscnun.2021041

Citation:

PDF (1382 KB)

Chemical Fixation of CO₂ Catalyzed by Functionalized Graphene Oxide

School of Chemistry and Chemical Engineering, Guangxi University//Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Nanning 530004, China

More Information

Received Date: March 14, 2021
Available Online: July 05, 2021

Graphical Abstract

Abstract

Abstract

The amino-functionalized imidazole ionic liquid (IL) was supported on graphene oxide (GO) and Santa Barbara Amorphous mesoporous molecular sieves (SBA-15) through the facile and simplified one-pot grafting approach to catalyze the synthesis of cyclic carbonates. The structure and thermal stability of the catalyst and the loading of the amino-functionalized imidazole IL were studied in detail with Fourier transforn infrared spectroscopy(FT-IR), scanning electron microscope(SEM), thermogravimetric analysis(TGA) and elemental analysis(EA). During the cycloaddition reaction, GO-NH₂ exhibited higher activity than SBA-15-NH₂. The optimum condition was 0.15 g catalyst, 130 ℃, 1.5 MPa CO₂ pressure and 5 h of reaction time, and the yield of propylene carbonate reached 96.46%. Furthermore, the supported catalyst exhibited promising recyclability and reusability for five consecutive reuses.
- cyclic carbonates,
- graphene oxide,
- ionic liquid,
- heterogeneous catalysis,
- epoxide,
- SBA-15

FullText(HTML)

References (33)

References

[1]	RASHIDI N A, YUSUP S. An overview of activated carbons utilization for the post-combustion carbon dioxide capture[J]. Journal of CO₂ Utilization, 2016, 13: 1-16. doi: 10.1016/j.jcou.2015.11.002
[2]	BHANIA P, MODAK A, BHAUMIK A. Porous organic polymers for CO₂ storage and conversion reactions[J]. ChemCatChem, 2019, 11(1): 244-257. doi: 10.1002/cctc.201801046
[3]	KAMPHUIS A J, PICCHIONI F, PESCARMONA P P. CO₂-fixation into cyclic and polymeric carbonates: principles and applications[J]. Green Chemistry, 2019, 21: 406-448. doi: 10.1039/C8GC03086C
[4]	LU X B, DARENSBOURG D J. Cobalt catalysts for the coupling of CO₂ and epoxides to provide polycarbonates and cyclic carbonates[J]. Chemical Society Reviews, 2012, 41: 1462-1484. doi: 10.1039/C1CS15142H
[5]	SRIVASTAVA R, D SRINIVAS, RATNASAMY P. Sites for CO₂ activation over amine-functionalized mesoporous Ti(Al)-SBA-15 catalysts[J]. Microporous & Mesoporous Materials, 2006, 90: 314-326. http://www.sciencedirect.com/science/article/pii/S1387181105005421
[6]	ZHANG X, NING Z, WEI W, et al. Chemical fixation of carbon dioxide to propylene carbonate over amine-functionalized silica catalysts[J]. Catalysis Today, 2006, 115: 102-106. doi: 10.1016/j.cattod.2006.02.028
[7]	JAGTAP S R, RAJE V P, SAMANT S D, et al. Silica supported polyvinyl pyridine as a highly active heterogeneous base catalyst for the synthesis of cyclic carbonates from carbon dioxide and epoxides[J]. Journal of Molecular Catalysis A Chemical, 2007, 266: 69-74. doi: 10.1016/j.molcata.2006.10.033
[8]	DAI W L, JIN B, LUO S L, et al. Novel functionalized guanidinium ionic liquids: efficient acid-base bifunctional catalysts for CO₂ fixation with epoxides[J]. Journal of Molecular Catalysis A Chemical, 2013, 378: 326-332. doi: 10.1016/j.molcata.2013.06.024
[9]	YU G R, ZHANG S J, ZHOU G H, et al. Structure, interaction and property of amino-functionalized imidazolium ILs by molecular dynamics simulation and ab initio calculation[J]. AICHE Journal, 2010, 53(12): 3210-3221. doi: 10.1002/aic.11339
[10]	BATES E D, MAYTON R D, NTAI I, et al. CO₂ capture by a task-specific ionic liquid[J]. Journal of the American Chemical Society, 2002, 124(6): 926-927. doi: 10.1021/ja017593d
[11]	CHEN J J, LI W W, LI X L, et al. Carbon dioxide capture by aminoalkyl imidazolium-based ionic liquid: a computational investigation[J]. Physical Chemistry Chemical Physics, 2012, 14(13): 4589-4596. doi: 10.1039/c2cp23642g
[12]	GUTOWSKI K E, MAGINN E J. Amine-functionalized task-specific ionic liquids: a mechanistic explanation for the dramatic increase in viscosity upon complexation with CO₂ from molecular simulation[J]. Journal of the American Chemical Society, 2008, 130(44): 14690-14704. doi: 10.1021/ja804654b
[13]	YU G R, ZHANG S J, YAO X Q, et al. Design of task-specific ionic liquids for capturing CO₂: a molecular orbital study[J]. Industrial & Engineering Chemistry Research, 2006, 45(8): 2875-2880. doi: 10.1021/ie050975y
[14]	YUE C, SU D, ZHANG X, et al. Amino-functional imidazolium ionic liquids for CO₂ activation and conversion to form cyclic carbonate[J]. Catalysis Letters, 2014, 144(7): 1313-1321. doi: 10.1007/s10562-014-1241-5
[15]	YUE S, WANG P, HAO X, et al. Dual amino-functionalized ionic liquids as efficient catalysts for carbonate synthesis from carbon dioxide and epoxide under solvent and cocatalyst-free conditions[J]. Journal of CO₂ Utilization, 2017, 21: 238-246. doi: 10.1016/j.jcou.2017.07.017
[16]	张灿鹏, 邵志刚. CO₂和CO分子在五边形石墨烯表面的吸附行为[J]. 华南师范大学学报(自然科学版), 2019, 51(1): 11-15. https://www.cnki.com.cn/Article/CJFDTOTAL-HNSF201901003.htm ZHANG C P, SHAO Z G. The adsorption behavior of CO₂ and coonpenta-Graphere[J]. Journl of South China Normal University (Natural Science Edition), 2019, 51(1): 11-15. https://www.cnki.com.cn/Article/CJFDTOTAL-HNSF201901003.htm
[17]	ZHANG M, CHU B, LI G Y, et al. Triethanolamine-modified mesoporous SBA-15: facile one-pot synthesis and its catalytic application for cycloaddition of CO₂ with epoxides under mild conditions[J]. Microporous & Mesoporous Materials, 2019, 274: 363-372. http://d.wanfangdata.com.cn/periodical/92a931c8b57c44e1e723a8274e823153
[18]	APPATURI N J, JOHAN M F, RAMALINGAM R J, et al. Highly efficient green mesostructured urea functionalized on SBA-15 catalysts for selective synthesis of benzlidenemalononitrile[J]. Microporous and Mesoporous Materials, 2018, 256: 67-74. doi: 10.1016/j.micromeso.2017.07.055
[19]	ZHANG S Q, LEE Y R, JEON H J, et al. Pd nanoparticles on a microporous covalent triazine polymer for H₂ production via formic acid decomposition[J]. Materials Letters, 2018, 215: 211-213. doi: 10.1016/j.matlet.2017.12.106
[20]	GUO L Y, DENG L L, JIN X C, et al. Composite ionic liquids immobilized on MCM-22 as efficient catalysts for the cycloaddition reaction with CO₂ and propylene oxide[J]. Catalysis Letters, 2017, 147: 2290-2297. doi: 10.1007/s10562-017-2137-y
[21]	LIU M, GAO K, LIANG L, et al. Insights into hydrogen bond donor promoted fixation of carbon dioxide with epoxides catalyzed by ionic liquids[J]. Physical Chemistry Chemical Physics, 2015, 17(8): 5959-5965. doi: 10.1039/C4CP05464D
[22]	LUO R, ZHOU X, FANG Y, et al. Metal- and solvent-free synthesis of cyclic carbonates from epoxides and CO₂ in the presence of graphite oxide and ionic liquid under mild conditions: a kinetic study[J]. Carbon, 2015, 82: 1-11. doi: 10.1016/j.carbon.2014.10.004
[23]	JIAN S, CHENG W, WEI F, et al. Reusable and efficient polymer-supported task-specific ionic liquid catalyst for cycloaddition of epoxide with CO₂[J]. Catalysis Today, 2009, 148: 361-367. doi: 10.1016/j.cattod.2009.07.070
[24]	ZHU J, GU Y K, WU J, et al. Aqueous grafting ionic liquid on graphene oxide for CO₂ cycloaddition[J]. Catalysis Letters, 2017, 147: 335-344. doi: 10.1007/s10562-016-1941-0
[25]	SUBHAN S, RAHMAN A U, YASEEN M, et al. Ultra-fast and highly efficient catalytic oxidative desulfurization of dibenzothiophene at ambient temperature over low Mn loaded Co-Mo/Al₂O₃ and Ni-Mo/Al₂O₃ catalysts using NaClO as oxidant[J]. Fuel, 2019, 237: 793-805. doi: 10.1016/j.fuel.2018.10.067
[26]	SUBHAN S, MUHAMMAD Y, SAHIBZADA M, et al. Studies on the selection of a catalyst oxidant system for the energy-efficient desulfurization and denitrogenation of fuel oil at mild operating conditions[J]. Energy and Fuels, 2019, 33(9): 8423-8439. doi: 10.1021/acs.energyfuels.9b01950
[27]	DAI W, ZHANG Y, TAN Y, et al. Reusable and efficient polymer nanoparticles grafted with hydroxyl-functionalized phosphonium-based ionic liquid catalyst for cycloaddition of CO₂ with epoxides[J]. Applied Catalysis A: General, 2016, 514: 43-50. doi: 10.1016/j.apcata.2016.01.004
[28]	QI C, YE J, WEI Z, et al. Polystyrene-supported amino acids as efficient catalyst for chemical fixation of carbon dioxide[J]. ChemInform, 2010, 352: 1925-1933. doi: 10.1002/adsc.201000261
[29]	XIAO L, DAN S, YUE C, et al. Protic ionic liquids: a highly efficient catalyst for synthesis of cyclic carbonate from carbon dioxide and epoxides[J]. Journal of CO₂ Utilization, 2014, 6: 1-6. doi: 10.1016/j.jcou.2014.01.004
[30]	KIM M I, KIM D K, BINEESH K V, et al. Catalytic performance of montmorillonite clay ion-exchanged with ionic liquids in the cycloaddition of carbon dioxide to allyl glycidyl ether[J]. Catalysis Today, 2013, 200: 24-29. doi: 10.1016/j.cattod.2012.04.049
[31]	SHI T Y, WANG J Q, SUN J, et al. Efficient fixation of CO₂ into cyclic carbonates catalyzed by hydroxyl-functionalized poly(ionic liquids)[J]. RSC Advances, 2013, 3(11): 3726-3732. doi: 10.1039/c3ra21872d
[32]	YU Y I, CHOI H J, SELVARAJ M, et al. Catalytic performance of polymer-supported ionic liquids in the cycloaddition of carbon dioxide to allyl glycidyl ether[J]. Reaction Kinetics, Mechanisms and Catalysis, 2011, 102(2): 353-365. doi: 10.1007/s11144-010-0280-1
[33]	MUHAMMAD Y, Ur RAHMAN A, Ur RASHID H, et al. Hydrodesulfurization of dibenzothiophene using Pd-promoted Co-Mo/Al₂O₃ and Ni-Mo/Al₂O₃ catalysts coupled with ionic liquids at ambient operating conditions[J]. RSC Advances, 2019, 9: 10371-10385. doi: 10.1039/C9RA00095J

Cited By

Cited by

Periodical cited type(1)

聂萌瑶，刘鑫. 考虑最大通信量的物联网群体访问路由算法. 计算机仿真. 2024(02): 415-419 .

Other cited types(3)

Get Citation

PDF

XML

Article views (754) PDF downloads (70) Cited by(4)

Turn off MathJax

Article Contents

Abstract

References

Chemical Fixation of CO2 Catalyzed by Functionalized Graphene Oxide

Abstract

References

Cited by

Periodical cited type(1)

Other cited types(3)

Catalog

Export File

Citation

Format

Content

Chemical Fixation of CO₂ Catalyzed by Functionalized Graphene Oxide