Preparation of Ni<sub>3</sub>S<sub>2</sub>-Ni@Ni Foam Electrode and Its Pseudocapacitance Properties

ZHAO Shaofei; LIU Peng; LI Wanping; ZENG Xiaohong; YU Lin; ZENG Huaqiang

doi:10.6054/j.jscnun.2020090

Journal of South China Normal University (Natural Science Edition) > 2020 > 52(6): 28-33. > DOI: 10.6054/j.jscnun.2020090

ZHAO Shaofei, LIU Peng, LI Wanping, ZENG Xiaohong, YU Lin, ZENG Huaqiang. Preparation of Ni₃S₂-Ni@Ni Foam Electrode and Its Pseudocapacitance Properties[J]. Journal of South China Normal University (Natural Science Edition), 2020, 52(6): 28-33. DOI: 10.6054/j.jscnun.2020090

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Preparation of Ni₃S₂-Ni@Ni Foam Electrode and Its Pseudocapacitance Properties

1.
School of Chemical Engineering & Light Industry, Guangdong University of Technology, Guangzhou 510006, China
2.
Nanobio laboratory, Singapore 138669, Singapore

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Received Date: February 29, 2020
Available Online: January 04, 2021

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Abstract

Abstract

Ni₃S₂ coated on well-designed hierarchical porous Ni@Ni foam (Ni₃S₂-Ni@NF) was fabricated with the novel method of hydrogen-bubble template electrodeposition and in-situ cyclic voltammetry electrodeposition. The physical phase and morphological properties of the as prepared samples were characterized with scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. The electrochemical capacitance properties were tested with an electrochemical workstation. The Ni₃S₂-Ni@NF electrode demonstrates a much higher specific capacitance of 4.56 F/cm² at a current density of 2 mA/cm². The Ni₃S₂-Ni@NF also exhibits excellent rate capability (4.06 F/cm² at a current density of 20 mA/cm²) and cycle performance (73% after 1 000 cycles).
- hydrogen-bubble,
- electrodeposition,
- supercapacitance,
- specific capacitance,
- cycle performance

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Preparation of Ni3S2-Ni@Ni Foam Electrode and Its Pseudocapacitance Properties

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Preparation of Ni₃S₂-Ni@Ni Foam Electrode and Its Pseudocapacitance Properties