The Synthesis of S-ZnO/rGO Composite Material and the Cycle Performance of Lead Acid Battery

XU Qiqin; MA Guozheng; WU Baozhu; CHEN Hongyu

doi:10.6054/j.jscnun.2020026

Journal of South China Normal University (Natural Science Edition) > 2020 > 52(2): 46-52. > DOI: 10.6054/j.jscnun.2020026

XU Qiqin, MA Guozheng, WU Baozhu, CHEN Hongyu. The Synthesis of S-ZnO/rGO Composite Material and the Cycle Performance of Lead Acid Battery[J]. Journal of South China Normal University (Natural Science Edition), 2020, 52(2): 46-52. DOI: 10.6054/j.jscnun.2020026

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The Synthesis of S-ZnO/rGO Composite Material and the Cycle Performance of Lead Acid Battery

School of Chemistry, South China Normal University, Guangzhou 510006, China

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Received Date: February 18, 2019
Available Online: March 21, 2021

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Abstract

Abstract

A simple and effective method was developed for preparing spherical zinc oxide/graphene (S-ZnO/rGO) composite material. In the synthesis process, GO prepared with the modified Humm3' method was dissolved in deionized water and mixed with S-ZnO powder. Then, the homogeneous solution was transferred to 100 mL PTFE lined stainless-steel autoclave and put into an oven at 180 ℃ for 12 h. The product was obtained with freeze-drying for 48 h. Subsequently, it was incorporated into the negative active materials at different dosages (0.5%, 1.0%, 1.5% and 2.0%) to prepare lead-acid batteries. The electrochemical properties of the batteries were studied. According to the results, the cycle life of the battery under the high-rate partial-state-of-charge (HRPSoC) condition showed the trend of first increasing and then decreasing with the doping amount of the S-ZnO/rGO composites increasing. The battery with 1.0% S-ZnO/rGO composite exhibited the best performance of HRPSoC cycle life, reaching 19 158 cycles, and it was improved by more than 165% compared with that of the ordinary lead-acid battery (7 210 cycles).
- S-ZnO/rGO composite,
- hydrothermal method,
- lead-acid battery,
- HRPSoC cycle life

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