张崧, 王玉海, 石光, 温钰环, 徐伟彬, 陈卓莉. 细菌纤维素/TiO2锂离子电池复合隔膜的研究[J]. 华南师范大学学报(自然科学版), 2017, 49(2): 21-27. doi: 10.6054/j.jscnun.2017091
引用本文: 张崧, 王玉海, 石光, 温钰环, 徐伟彬, 陈卓莉. 细菌纤维素/TiO2锂离子电池复合隔膜的研究[J]. 华南师范大学学报(自然科学版), 2017, 49(2): 21-27. doi: 10.6054/j.jscnun.2017091
ZHANG Song, WANG Yuhai, SHI Guang, WEN Yuhuan, CHEN Zhuoli, . Study on Bacterial Cellulose/TiO2 Composite Separators for Lithium-ion Batteries[J]. Journal of South China Normal University (Natural Science Edition), 2017, 49(2): 21-27. doi: 10.6054/j.jscnun.2017091
Citation: ZHANG Song, WANG Yuhai, SHI Guang, WEN Yuhuan, CHEN Zhuoli, . Study on Bacterial Cellulose/TiO2 Composite Separators for Lithium-ion Batteries[J]. Journal of South China Normal University (Natural Science Edition), 2017, 49(2): 21-27. doi: 10.6054/j.jscnun.2017091

细菌纤维素/TiO2锂离子电池复合隔膜的研究

Study on Bacterial Cellulose/TiO2 Composite Separators for Lithium-ion Batteries

  • 摘要: 利用细菌纤维素(BC)的纳米纤维与纳米TiO2颗粒进行溶液混合制备具有多孔、极性和良好热稳定性的BC/TiO2锂离子电池隔膜,并对其孔结构、亲液性、热稳定性、电化学稳定性、离子电导率和电池性能循环稳定性等性能进行研究. 结果表明,BC/TiO2复合膜具有三维多孔结构、良好吸液性和高温尺寸稳定性.相对于商品化隔膜(Celgard?2325),BC/TiO2隔膜具有更高的离子电导率,并且随着纳米TiO2含量的增加,离子电导率先升高后降低,当纳米TiO2质量分数为20.81 %时,BC/TiO2复合膜具有最大的室温离子电导率(1.7010-3 S/cm). BC/TiO2复合膜作为锂离子电池隔膜时,电池具有较好的循环稳定性和倍率性能. 该研究对制备优异热稳定性和离子电导率的锂离子电池隔膜具有指导意义.

     

    Abstract: Bacterial cellulose (BC)/TiO2 composite membranes with porous, polar and good thermal stability as novel separator for lithium ion battery were prepared by using TiO2 nanoparticles prepared by sol-gel method to mix with BC nanofibers. The pore structure, lyophilic performance, thermal stability, electrochemical stability, ionic conductivity and battery cycling stability of the composite membranes were characterized by a variety of techniques. The research results indicated that BC/TiO2 composite membranes have a three-dimensional porous structure, good electrolyte absorptivity and dimensional stability at high temperature. Compared to the commercial membrane (Celgard?2325), BC/TiO2 composite separators have higher ionic conductivity. With the increase of TiO2 nanoparticles content, the ionic conductivity increased at first and decreased subsequently. When the content of TiO2 nanoparticles is 20.81 %, the BC/TiO2 composite separator has the highest ionic conductivity (1.7010-3S/cm). When used the composite membranes as the separators for lithium ion battery, the battery shows its good cyclic stability and high rate discharge performance. This research has a guiding significance in the preparation of lithium ion battery separator with excellent thermal stability and ionic conductivity.

     

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