吕梅香, 廖添, 宋亭, 曾健, 曾和平*. 三聚氰胺-环三磷腈阻燃剂的制备及其应用[J]. 华南师范大学学报（自然科学版）, 2015, 47(2): 78-83. doi: 10.6054/j.jscnun.2014.12.011
引用本文: 吕梅香, 廖添, 宋亭, 曾健, 曾和平*. 三聚氰胺-环三磷腈阻燃剂的制备及其应用[J]. 华南师范大学学报（自然科学版）, 2015, 47(2): 78-83. doi: 10.6054/j.jscnun.2014.12.011
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Lv Meixiang, Liao Tian, Song Ting, Zeng Jian, Zeng Heping*. Preparation and Application of Cyclotriphosphazene Modified with Etherized Hexamethylolmelamine[J]. Journal of South China Normal University (Natural Science Edition), 2015, 47(2): 78-83. doi: 10.6054/j.jscnun.2014.12.011
Citation: Lv Meixiang, Liao Tian, Song Ting, Zeng Jian, Zeng Heping*. Preparation and Application of Cyclotriphosphazene Modified with Etherized Hexamethylolmelamine[J]. Journal of South China Normal University (Natural Science Edition), 2015, 47(2): 78-83. doi: 10.6054/j.jscnun.2014.12.011
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三聚氰胺-环三磷腈阻燃剂的制备及其应用

Preparation and Application of Cyclotriphosphazene Modified with Etherized Hexamethylolmelamine

    摘要
  • 摘要: 磷腈化合物是一类无卤、对环境友好且具有生物相容性的低毒性阻燃剂，但大部分磷腈衍生物是油溶性的，需要通过熔融共混、辊轧等方式才能制成阻燃纤维、塑料，操作工艺复杂，无法直接用于天然纤维，因此大大限制了其应用范围．该文以六羟甲基三聚氰胺和六氯环三磷腈为原料，通过亲核取代、醚化两步法合成了一种水溶性、醇溶性无卤磷腈阻燃剂.用红外光谱(FTIR)、核磁共振谱(^1H NMR、^13C NMR、^31P NMR)和电喷雾电离质谱(ESI-MS)等进行了结构表征，证明其为无氯、P螺原子链接的目标化合物．将该阻燃剂用

     

    Abstract: The phosphazenebased compounds are halogenfree and environmentallyfriendly. Some of them are biocompatible and can be used as flame resistant materials. However, these compounds often lack watersoluble. Some reports attempted to produce a fireretar

     

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