CATALYTIC PERFORMANCE OF PEROVSKITE-LIKE OXIDES LA1.6BA0.4MO4(M=CO、NI、CU)FOR NO DIRECT DECOMPOSITION
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Abstract
The K2NiF4 type oxides,La1.6Ba0.4MO4(M=Co、Ni、Cu)complex oxides were prepared by citrate combustion method.The characters of these samples were analyzed by XRD and H2-TPR.At the same time,the catalytic activity for NO direct decomposition was also tested.The results demonstrated that the influence to the oxide capability of the various transitional metal at B site was different while Ba substituded for La,but the doping of Ba promotes the redox capability of catalysts and leads to good catalytic performance ultimately.It was found that Ni-base perovskite-like oxides performed the best activity.
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