Improvement of Luminescent Properties of NaMgBO3∶Ce3+ Phosphors by Compositing YBO3∶Ce3+
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Abstract
A series of NaMgBO3∶Ce3+/yYBO3∶Ce3+ (composite ratioy=0~0.035, mole ration) phosphors were prepared by a second-phase composite method, and their phase, morphology and optical properties were investigated. When YBO3∶5%Ce3+ was chosen as the complex substrate and composited into the NaMgBO3∶Ce3+ phosphor, the band gap of the sample increased, and the emission intensity of the sample at 464 nm was gradually enhanced with the increase of the YBO3∶Ce3+ composite ratio, and the optimal ratio y was 0.025. Since the emission peak of YBO3∶Ce3+in the range of 380-400 nm overlaps with the NaMgBO3∶Ce3+ excitation peak, and the emission intensity of the composite sample in this range will decrease with the increase of the mass concentration of YBO3∶Ce3+, which proves the existence of energy transfer between YBO3∶Ce3+ and NaMgBO3∶Ce3+. The results show that this phosphor can be a good candidate for cyan filling in full-spectrum illumination.
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