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JIN Xiaoqi, GE Jinlong, ZHANG Liyuan, XIONG Mingwen, WU Zhong, MENG Xiaolin. The Self-assembly Synthesis and CO2 Adsorption Property of Boron-doped Mesoporous C/SiO2 Composites[J]. Journal of South China Normal University (Natural Science Edition), 2022, 54(4): 48-55. DOI: 10.6054/j.jscnun.2022057
Citation: JIN Xiaoqi, GE Jinlong, ZHANG Liyuan, XIONG Mingwen, WU Zhong, MENG Xiaolin. The Self-assembly Synthesis and CO2 Adsorption Property of Boron-doped Mesoporous C/SiO2 Composites[J]. Journal of South China Normal University (Natural Science Edition), 2022, 54(4): 48-55. DOI: 10.6054/j.jscnun.2022057

The Self-assembly Synthesis and CO2 Adsorption Property of Boron-doped Mesoporous C/SiO2 Composites

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  • Received Date: April 28, 2022
  • Available Online: September 21, 2022
  • A serias of novel mesoporous carbon/silica composites (BC/SiO2) with abundant mesoporous structure were successfully prepared with the sol-gel self-assembly method, wherein triblock copolymer F127 was used as a template, tetraethoxysilane was used as an inorganic silicon precursor, and phenolic resin and triisopropyl borate were selected as C- and B- containing precursors. Meanwhile, the effect of the content of boron doped on the CO2 capture capacity of BC/SiO2 composites was investigated and the adsorption isotherms of CO2 were determined. The results were fitted and analyzed using three kinds of adsorption isotherms models (Langmuir, Freundlich and DSL models). These results demonstrated that the BC/SiO2 composites exhibited a spherical shape and had a high specific surface area and uniform pore distribution and a large amount of boron atoms was uniformly doped in the carbon framework of BC/SiO2 composite, which introduced the polar sites. The capability of capturing CO2 was not only related to the specific surface area of the composite material but also to the number of polar sites generated by doped boron. It was found that the adsorption CO2 molecules on BC/SiO2 composites presented two adsorption sites with different degrees and adsorption isotherms of CO2 were highly consistent with the DSL model.
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