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DU Shuaihang, YUE Lu, GUAN Rongfeng, YANG Xiuli, XU Ning, ZHANG Wenhui. The Effect of Fe(Ⅲ) Doping on Structure and Gas Sensing Properties of Ultrathin W18O49 Nanowires[J]. Journal of South China Normal University (Natural Science Edition), 2021, 53(3): 22-28. DOI: 10.6054/j.jscnun.2021039
Citation: DU Shuaihang, YUE Lu, GUAN Rongfeng, YANG Xiuli, XU Ning, ZHANG Wenhui. The Effect of Fe(Ⅲ) Doping on Structure and Gas Sensing Properties of Ultrathin W18O49 Nanowires[J]. Journal of South China Normal University (Natural Science Edition), 2021, 53(3): 22-28. DOI: 10.6054/j.jscnun.2021039

The Effect of Fe(Ⅲ) Doping on Structure and Gas Sensing Properties of Ultrathin W18O49 Nanowires

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  • Received Date: January 20, 2021
  • Available Online: July 05, 2021
  • Fe(Ⅲ)-doped ultrathin tungsten oxide (Fe-W18O49) nanowires were prepared with the simple solvent-thermal method to optimize the acetone-sensing performance of tungsten oxide acetone sensor materials for reason of the low response, poor selectivity and high detection temperature of pure tungsten oxide. The results showed that Fe(Ⅲ) doping not only inhibited the transformation of W18O49 crystal phase to WO3 crystal phase but also optimized its gas-sensing performance. The W18O49 nanowires with doping ratio (n(Fe)/n(W)) of 0.10 demonstrated the best performance. This material showed a sensitivity of 11.4 for acetone with a volume fraction of 5×10-5 at the optimum operating temperature of 220 ℃, with the response/recovery time of 14/16 s and good selectivity.
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