Preparation and Luminescence Properties of Na2Ca2.92Si6O16:0.08Eu3+ Phosphors

GAO Shijie; WANG Hua; ZHANG Shanshan; QIAO Li; MAO Jinlong

doi:10.6054/j.jscnun.2019059

Journal of South China Normal University (Natural Science Edition) > 2019 > 51(4): 21-25. > DOI: 10.6054/j.jscnun.2019059

GAO Shijie, WANG Hua, ZHANG Shanshan, QIAO Li, MAO Jinlong. Preparation and Luminescence Properties of Na₂Ca_2.92Si₆O₁₆:0.08Eu³⁺ Phosphors[J]. Journal of South China Normal University (Natural Science Edition), 2019, 51(4): 21-25. DOI: 10.6054/j.jscnun.2019059

Citation:

PDF (851 KB)

Preparation and Luminescence Properties of Na₂Ca_2.92Si₆O₁₆:0.08Eu³⁺ Phosphors

1.
Experimental Center, Shandong University of Traditional Chinese Medicine, Jinan 250355, China
2.
College of Science and Technology, Shandong University of Traditional Chinese Medicine, Jinan 250355, China
3.
School of Pharmacy, Shandong University of Traditional Chinese Medicine, Jinan 250355, China

More Information

Received Date: March 14, 2019
Available Online: March 21, 2021

Graphical Abstract

Abstract

Abstract

A series of Na₂Ca_3-xSi₆O₁₆:xEu³⁺ was prepared with high temperature solid-state reaction and structurally characterized with X-ray powder diffraction. The results of X-ray powder diffraction showed that Eu³⁺-doping had no significant effect on the crystal structure of Na₂Ca₃Si₆O₁₆:Eu³⁺. Its optical properties were checked with the spectrofluorometer. The results showed that the Na₂Ca_3-xSi₆O₁₆:xEu³⁺ phosphor emitted red light with the strongest emission peak at 611 nm. The doping of Eu³⁺ did not change the peak shape and position of the emission spectra of Na₂Ca_3-xSi₆O₁₆:xEu³⁺phosphor. However, the doping content (mole fraction) of Eu³⁺ was related to the luminescence intensity. When the concentration of Eu³⁺ was 0.08, the Na₂Ca_3-xSi₆O₁₆:xEu³⁺ showed the strongest luminescence intensity. The concentration quenching was observed when Eu³⁺ concentration was over 0.08, and the concentration quenching mechanism was verified as multipole-multipole interaction. The results indicated that Na₂Ca_2.92Si₆O₁₆:0.08Eu³⁺ phosphor was a potential red light-emitting material for white LED.
- silicate,
- phosphor,
- high temperature solid-state reaction,
- luminescence properties,
- Eu³⁺

FullText(HTML)

References (23)

References

[1]	雷玉堂, 黎慧.未来的照明光源:白光LED技术及其发展[J].光学与光电技术, 2003, 1(5):33-34. doi: 10.3969/j.issn.1672-3392.2003.05.009 LEI Y T, LI H. Lighting source in the future:white-light IED[J]. Optics & Optoelectronic Technology. 2003, 1(5):33-34. doi: 10.3969/j.issn.1672-3392.2003.05.009
[2]	ZHOU Y, ZHU C, ZHANG M, et al. Optical properties of Eu-and Dy-doped calcium aluminoborosilicate glasses for LED applications[J]. Journal of Alloys & Compounds, 2016, 688:715-720. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=842485864632670019e1be96730f3cac
[3]	ZHANG X G, ZHOU F X, SHI J X, et al. Sr_3.5Mg_0.5Si₃O₈Cl₄:Eu²⁺ bluish-green-emitting phosphor for NUV-based LED[J]. Materials Letters, 2009, 63(11):852-854. doi: 10.1016/j.matlet.2009.01.024
[4]	王泽忠, 汪克风, 杜发钊, 等.稀土荧光/聚碳酸酯加工可行性探讨及其荧光性能研究[J].华南师范大学学报(自然科学版), 2015, 47(1):32-37. http://www.cnki.com.cn/Article/CJFDTotal-HNSF201501006.htm WANG Z Z, WANG K F, DU F Z, et al. Study on processing feasibility and fluorescence properties of rare-earth fluorescent/polycarbonate[J]. Journal of South China Normal University (Natural Science Edition), 2015, 47(1):32-37. http://www.cnki.com.cn/Article/CJFDTotal-HNSF201501006.htm
[5]	YU Q M, LIU Y F, WU S, et al. Luminescent properties of Ca₂SiO₄:Eu ³⁺ red phosphor trichromatic white light emitting diodes[J]. Journal of Rare Earths, 2008, 26(6):783-786. doi: 10.1016/S1002-0721(09)60005-3
[6]	LI L, TANG X H, JIANG Z Q, et al. NaBaLa₂(PO₄)₃:a novel host lattice for Sm³⁺-doped phosphor materials emitting reddish-orange light[J]. Journal of Alloys and Compounds, 2017, 701:515-523. doi: 10.1016/j.jallcom.2017.01.171
[7]	LIAN J B, QIN H, LIANG P, et al, Co-precipitation synthesis of Y₂O₂SO₄:Eu³⁺ nanophosphor and comparison of photoluminescence properties with Y₂O₂:Eu³⁺ and Y₂O₂S: Eu³⁺ nanophosphors[J]. Solid State Sciences, 2015, 48:147-154. doi: 10.1016/j.solidstatesciences.2015.08.004
[8]	ZHAO G S, LIU W, LOU Z H, et al. Hydrothermal synthesis and photoluminescence properties of In³⁺ co-doped YVO₄:Eu³⁺ phosphors[J]. Advanced Powder Technology, 2016, 27(4):1225-1232. doi: 10.1016/j.apt.2016.04.008
[9]	CHEN G W, LI Y B, QI W C, et al. Morphology-tailored synthesis and luminescent properties of Y₂O₃:Eu³⁺ phosphors[J]. Journal of Materials Science-Materials in Electronics, 2018, 29(4):2841-2847. doi: 10.1007/s10854-017-8213-7
[10]	杨洁, 陈锐彬, 万霞, 等. Dy³⁺/Eu³⁺共掺钒酸钇荧光粉的合成及发光性质研究[J].华南师范大学学报(自然科学版), 2011(2):81-86. http://www.cnki.com.cn/Article/CJFDTotal-HNSF201102021.htm YANG J, CHEN R B, WAN X, et al. Synthesis and luminescence properties of Dy³⁺/Eu³⁺ co-doped YVO₄ phosphors[J]. Journal of South China Normal University (Natural Science Edition), 2011(2):81-86. http://www.cnki.com.cn/Article/CJFDTotal-HNSF201102021.htm
[11]	KIRM M, FELDBACH E, MAGI H, et al. Silicate apatite phosphors for pc-LED applications[J]. Proceedings of the Estonian Academy of Sciences, 2017, 66(4):383-395. doi: 10.3176/proc.2017.4.14
[12]	CHEN H Y, WENG M H, CHANG S J, et al. Preparation of Sr₂SiO₄:Eu³⁺ phosphors by microwave-assisted sintering and their luminescent properties[J]. Ceramics International, 2012, 38(1):125-130. doi: 10.1016/j.ceramint.2011.06.044
[13]	WANG Z J, GUO S Q, LI Q X, et al. Luminescent properties of Ba₂SiO₄:Eu³⁺ for white light emitting diodes[J]. Physica B:Condensed Matter, 2013, 411:110-113. doi: 10.1016/j.physb.2012.11.040
[14]	WU Y, WANG Y S, HE D W, et al. Synthesis of the Zn₂SiO₄: Eu³⁺ red phosphor by sol-gel method[J]. Spectroscopy and Spectral Analysis, 2011, 31(4):890-893. http://d.old.wanfangdata.com.cn/Periodical/zgxtxb-e201204008
[15]	KAHLENBERG V, GIRTLER D, ARROYAB E, et al. (Na₂Ca₃Si₆O₁₆)-structural, spectroscopic and computational investigations on a crystalline impurity phase in industrial soda-lime glasses[J]. Mineralogy and Petrology, 2010, 100(1/2):1-9. doi: 10.1007/s00710-010-0116-8
[16]	BARROS B S, OLIVEIRA R S D, KULESZA J, et al. Reddish-orange Ca_3-xAl₂O₆:xEu³⁺, nanophosphors:fast synthesis and photophysical properties[J]. Journal of Physics & Chemistry of Solids, 2015, 78:90-94. https://www.sciencedirect.com/science/article/abs/pii/S0022369714002856
[17]	JIA C Y, HUANG Z, TIAN X Y, et al. Synthesis and photoluminescence properties of a novel BaGe₄O₉:Eu³⁺ red emitting phosphor for warm white LEDs[J]. Dyes and Pigments, 2019, 160:772-778. doi: 10.1016/j.dyepig.2018.09.012
[18]	郎集会, 孙雨婷, 李香兰, 等.稀土Eu掺杂ZnO纳米棒的水热合成及其光学性质[J].华南师范大学学报(自然科学版), 2018, 50(2):25-29. http://d.old.wanfangdata.com.cn/Periodical/hnsfdx201802005 LANG J H, SUN Y T, LI L X, et al. Hydrothermal synthesis and optical properties of Eu－doped ZnO nanorods[J]. Journal of South China Normal University (Natural Science Edition), 2018, 50(2):25-29. http://d.old.wanfangdata.com.cn/Periodical/hnsfdx201802005
[19]	SAKTHIVEL T, ANNADURAI G, VIJAYAKUMAR R, et al. Synthesis, luminescence properties and thermal stability of Eu³⁺-activated Na₂Y₂B₂O₇ red phosphors excited by near-UV light for pc-WLEDs[J]. Journal of Luminescence, 2019, 205:129-135. doi: 10.1016/j.jlumin.2018.09.008
[20]	van UITER L G. Characterization of energy transfer interactions between rare earth ions[J]. Journal of The Electrochemical Society, 1967, 114(10):1048-1053. doi: 10.1149/1.2424184
[21]	BLASSE G, GRABMAIER B C. Luminescent Materials[M]. Berlin: Springer-Verlag, 1994: 91-106.
[22]	ZHU M M, PAN Y X, HUANG Y Q, et al. Designed synthesis, morphology evolution and enhanced photoluminescence of a highly efficient red dodec-fluoride phosphor, Li₃Na₃Ga₂F₁₂:Mn⁴⁺, for warm WLEDs[J]. Journal of Materials Chemistry C, 2018, 6(3):491-499. doi: 10.1039/C7TC04878E
[23]	BLASSE G. Energy transfer in oxidic phosphors[J]. Physics Letters A, 1968, 28(6):444-445. doi: 10.1016/0375-9601(68)90486-6

Cited By

Cited by

Periodical cited type(1)

王建彬，唐孝生，周笔，曾夏辉，黎金城，周赢武. PCE10显著提升三元倍增型有机光电探测器红光与近红外光探测能力. 发光学报. 2023(12): 2222-2230 .

Other cited types(0)

Get Citation

PDF

XML

Article views (1705) PDF downloads (55) Cited by(1)

Turn off MathJax

Article Contents

Abstract

References

Preparation and Luminescence Properties of Na2Ca2.92Si6O16:0.08Eu3+ Phosphors

Abstract

References

Cited by

Periodical cited type(1)

Other cited types(0)

Catalog

Export File

Citation

Format

Content

Preparation and Luminescence Properties of Na₂Ca_2.92Si₆O₁₆:0.08Eu³⁺ Phosphors