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铜表面镍-石墨烯的电沉积制备及耐腐蚀性能

马久明 宋士虎 冼明锏 卢东亮 陈先义 鲁圣国

马久明, 宋士虎, 冼明锏, 卢东亮, 陈先义, 鲁圣国. 铜表面镍-石墨烯的电沉积制备及耐腐蚀性能[J]. 华南师范大学学报(自然科学版), 2020, 52(4): 43-49. doi: 10.6054/j.jscnun.2020059
引用本文: 马久明, 宋士虎, 冼明锏, 卢东亮, 陈先义, 鲁圣国. 铜表面镍-石墨烯的电沉积制备及耐腐蚀性能[J]. 华南师范大学学报(自然科学版), 2020, 52(4): 43-49. doi: 10.6054/j.jscnun.2020059
MA Jiuming, SONG Shihu, XIAN Mingjian, LU Dongliang, CHEN Xianyi, LU Shengguo. Electroplating Preparation and Anticorrosion Behavior of Ni-Graphene on Copper Surface[J]. Journal of South China normal University (Natural Science Edition), 2020, 52(4): 43-49. doi: 10.6054/j.jscnun.2020059
Citation: MA Jiuming, SONG Shihu, XIAN Mingjian, LU Dongliang, CHEN Xianyi, LU Shengguo. Electroplating Preparation and Anticorrosion Behavior of Ni-Graphene on Copper Surface[J]. Journal of South China normal University (Natural Science Edition), 2020, 52(4): 43-49. doi: 10.6054/j.jscnun.2020059

铜表面镍-石墨烯的电沉积制备及耐腐蚀性能

doi: 10.6054/j.jscnun.2020059
基金项目: 

国家自然科学基金项目 51872053

国家自然科学基金委-广东省联合基金项目 500160009

详细信息
    通讯作者:

    鲁圣国,教授,Email:sglu@gdut.edu.cn

  • 中图分类号: TB34

Electroplating Preparation and Anticorrosion Behavior of Ni-Graphene on Copper Surface

  • 摘要: 采用电沉积方法,将石墨烯与镍离子共沉积到被保护的铜基底上,制备了镍-石墨烯复合镀层.通过X射线衍射(XRD)、扫面电子显微镜(SEM)等方法对复合材料的物质结构、表面形貌特征进行了表征,采用海水浸泡方法研究了复合材料的抗腐蚀性能.结果表明:当电流密度为5 A/dm2时,共沉积方法制备的镍-石墨烯复合镀层平整连续,晶粒较小,石墨烯穿插于多个镍颗粒之间,将镍颗粒包裹于其中,能有效阻断海水中的酸根、碱性离子对铜基底的腐蚀作用,明显增强了复合材料的耐腐蚀性.此研究对船舶及海洋工程金属构件的抗海水腐蚀方法具有一定的参考价值.
  • 图  1  石墨烯的XRD谱和SEM图

    Figure  1.  The XRD pattern and SEM image of graphene

    图  2  铜表面Ni镀层及Ni-rGO镀层的XRD谱

    Figure  2.  The XRD pattern of pure nickel coating and Ni-rGO co-deposited coating on copper surface

    图  3  铜表面镀Ni后样品表面及其横截面的SEM图

    Figure  3.  The SEM of surface and cross section of sample after electroplating Ni on copper sheet

    图  4  铜表面共沉积Ni-rGO镀层后样品表面及横截面的SEM图

    Figure  4.  The SEM of surface and cross section of the sample after co-depositing Ni-rGO coating on copper sheet

    图  5  不同样品的塔菲尔曲线及腐蚀速率

    Figure  5.  The Tafel plots and corrosion rates of different samples

    图  6  海水腐蚀60 d前后不同样品的SEM图

    Figure  6.  The SEM images of different samples after seawater corrosion for 60 days

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出版历程
  • 收稿日期:  2019-12-19
  • 刊出日期:  2020-08-25

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