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不同锂源对富锂锰基Li1.133Mn0.466Ni0.2Co0.2O2正极材料性能的影响研究

林赞锐 沈家东 沈楷翔 马少蒙 侯贤华

林赞锐, 沈家东, 沈楷翔, 马少蒙, 侯贤华. 不同锂源对富锂锰基Li1.133Mn0.466Ni0.2Co0.2O2正极材料性能的影响研究[J]. 华南师范大学学报(自然科学版), 2015, 47(6): 37-41.
引用本文: 林赞锐, 沈家东, 沈楷翔, 马少蒙, 侯贤华. 不同锂源对富锂锰基Li1.133Mn0.466Ni0.2Co0.2O2正极材料性能的影响研究[J]. 华南师范大学学报(自然科学版), 2015, 47(6): 37-41.
Research in the Influence of Different Source of Lithium on the Performance of Lithium-rich Manganese-based Li1.133 Mn0.466 Ni0.2 Co0.2 O2 Cathode Material[J]. Journal of South China normal University (Natural Science Edition), 2015, 47(6): 37-41.
Citation: Research in the Influence of Different Source of Lithium on the Performance of Lithium-rich Manganese-based Li1.133 Mn0.466 Ni0.2 Co0.2 O2 Cathode Material[J]. Journal of South China normal University (Natural Science Edition), 2015, 47(6): 37-41.

不同锂源对富锂锰基Li1.133Mn0.466Ni0.2Co0.2O2正极材料性能的影响研究

基金项目: 

国家自然科学基金项目;广东省自然科学基金项目

详细信息
    通讯作者:

    侯贤华

  • 中图分类号: O78

Research in the Influence of Different Source of Lithium on the Performance of Lithium-rich Manganese-based Li1.133 Mn0.466 Ni0.2 Co0.2 O2 Cathode Material

Funds: 

The National Natural Science Foundation of China

  • 摘要: 采用共沉淀的方法将含有一定比例的镍、钴、锰的金属醋酸盐溶液均匀混合,然后加入适当的沉淀剂Na2CO3制备前驱体Mn0.466Ni0.2Co0.2CO3,最后分别与不同锂源(Li2CO3、LiOH)混合煅烧得到富锂锰基Li1.133Mn0.466Ni0.2Co0.2O2正极材料。采用XRD和SEM分别对不同锂源制备的Li1.133Mn0.466Ni0.2Co0.2O2的结构和表面形貌进行表征,采用恒电流充放电和循环伏安法测试对不同锂源制备的Li1.133Mn0.466Ni0.2Co0.2O2的电化学性能进行测试。结果表明,以LiOH为锂源合成的样品在0.1C倍率下首次充、放电比容量分别为330.1mAh/g和218.6mAh/g,首次库仑效率为66.23%,在1C倍率内表现为优秀的稳定循环比容量特性,但是在2C以及2C以上高倍率循环稳定性不及以Li2CO3为锂源合成的样品性能。
  • [1] Xiaobo Li, Mengqing Xu, Yanjing Chen, et al.Surface study of electrodes after long-term cycling in Li1.2Ni0.15Mn0.55Co0.1O2–graphite lithium-ion cellsOriginal Research Article [J]. Journal of Power Sources, 2014, 248: 1077-1084.[J].Journal of Power Sources,, 2014, 248:1077-1084 [2]T. Nagaura, K. Tozawak. .Nagaura, K. Tozawak. Lithium ion rechargeable battery [J]. Prog. Batts. Sol.Cells, 1990, 9:209-217.[J].Prog. Batts. Sol.Cells, 1990, 9:209-217 [3] 储艳秋.锂离子电池薄膜电极材料的制备及其电化学性质研究[D].上海.复旦大学.2003. [4] Joo Gon Kim, Byungrak Son, Santanu Mukherjee, et al.A review of lithium and non-lithium based solid state batteries Review Article [J].Journal of Power Sources, 2015, 282:299-322.[J].Journal of Power Sources, 2015, 282:299-322 [5] Ying Zhang, Ke Ye, Kui Cheng, et al.Three-dimensional lamination-like P2-Na2/3Ni1/3Mn2/3O2 assembled with two-dimensional ultrathin nanosheets as the cathode material of an aqueous capacitor batteryOriginal Research Article [J].Electrochimica Acta, 2014, 148:195-202.[J].Electrochimica Acta, 2014, 148:195-202 [6]徐玲荣,孙建红,叶琴.锂离子电池正极材料的研究与应用现状探究[J].化学工程与装备, 2012, (1):105-105 [7]Xianhua Hou,Yangling Huang, Shaomeng Ma, et al.Facile hydrothermal method synthesis of coralline-like Li1.2Mn0.54Ni0.13Co0.13O2 hierarchical architectures as superior cathode materials for lithium-ion batteries [J].Materials Research Bulletin, ,2015, 63:256-264 [8]黄果, 杨顺毅,雷钢铁,等.十正极材料的喷雾干燥法合成及电化学性能[J].中国有色金属学报, 2014, 24(3):725-732 [9]Xianhua Hou, Xiaoli Zou, Yanling Huang, et al.Surfactant CTAB-assisted synthesis of Li113[Ni0.233Mn0.534Co0.233]0.87O2 with festoon-like hierarchical architectures as cathode materials for Li-ion batteries with outstanding performance[J].RSC Advances, 2014, 4(56):29534-29541 [10]Chenhao Zhao, Qiang Shen.Organic acid assisted solid-state synthesis of Li12Ni0.16Co0.08Mn0.56O2 nanoparticles as lithium ion battery cathodesOriginal Research Article[J].Current Applied Physics, 2014, 14(12):1849-1853 [11] Shoaib Muhammad, Sangwoo Lee, Hyunchul Kim, et al.Deciphering the thermal behavior of lithium rich cathode material by in situ X-ray diffraction techniqueOriginal Research Article [J].Journal of Power Sources, 2015, 285:56-160 [12]Jan Geder, Jay Hyok Song, Sun Ho Kang, et al.Thermal stability of lithium-rich manganese-based cathode Original Research Article[J].Solid State Ionics, 2014, 268(Part B):242-246 [13] Fan Yang, Qinggang Zhang, Xiaohong Hu, et al.Synthesis of layered xLi2MnO3?(1 ? x)LiMnO2 nanoplates and its electrochemical performance as Li-rich cathode materials for Li-ion batteryOriginal Research Article[J].Electrochimica Acta, 2015, 165:182-190 [14] Jingwen Zhang, Xun Guo, Sumei Yao, Wentao Zhu, et al.Tailored synthesis of Ni0.25Mn0.75CO3 spherical precursors for high capacity Li-rich cathode materials via a urea-based precipitation method[J].Journal of Power Sources, 2013, 238:245-250 [15] Xiukang Yang, Xianyou Wang, Guishan Zou, et al.Spherical lithium-rich layered Li1.13[Mn0.534Ni0.233Co0.233]0.87O2 with concentration-gradient outer layer as high-performance cathodes for lithium ion batteriesOriginal Research Article[J].Journal of Power Sources, 2013, 232:338-347 [16]Jae-Won Lee, Doosung Hwang.Application of thermodynamic activity models to the equilibrium potential for lithium intercalation process of a cobalt-free cathode material with a layered structureOriginal Research Article[J].Computational Materials Science, 2015, 100(Part A):80-83 [17] Jun Wang, Bao Qiu, Hailiang Cao, et al.Electrochemical properties of 0.6Li[Li1/3Mn2/3]O2–0.4LiNixMnyCo1?x?yO2 cathode materials for lithium-ion batteriesOriginal Research Article[J].Journal of Power Sources, 2012, 218:128-133 [18]Chenhao Zhao, Qiang Shen.Organic acid assisted solid-state synthesis of Li12Ni0.16Co0.08Mn0.56O2 nanoparticles as lithium ion battery cathodesOriginal Research Article[J].Current Applied Physics, 2014, 14(12):1849-1853 [19]J.M. Zheng,XB. Wu,Y. Yang.A comparison of preparation method on the electrochemical performance of cathode material Li[Li0.2Mn0.54Ni0.13Co0.13]O2 for lithium ion battery Original Research Article[J].Electrochimica Acta, 2011, 56(8):3071-3078 [20]Ho-Hyun Sun, Wonchang Choi, Joong Kee Lee, et al.Control of electrochemical properties of nickel-rich layered cathode materials for lithium ion batteries by variation of the manganese to cobalt ratioOriginal Research Article[J].Journal of Power Sources, 2015, 275: 877-883

    [1] Xiaobo Li, Mengqing Xu, Yanjing Chen, et al.Surface study of electrodes after long-term cycling in Li1.2Ni0.15Mn0.55Co0.1O2–graphite lithium-ion cellsOriginal Research Article [J]. Journal of Power Sources, 2014, 248: 1077-1084.[J].Journal of Power Sources,, 2014, 248:1077-1084 [2]T. Nagaura, K. Tozawak. .Nagaura, K. Tozawak. Lithium ion rechargeable battery [J]. Prog. Batts. Sol.Cells, 1990, 9:209-217.[J].Prog. Batts. Sol.Cells, 1990, 9:209-217 [3] 储艳秋.锂离子电池薄膜电极材料的制备及其电化学性质研究[D].上海.复旦大学.2003. [4] Joo Gon Kim, Byungrak Son, Santanu Mukherjee, et al.A review of lithium and non-lithium based solid state batteries Review Article [J].Journal of Power Sources, 2015, 282:299-322.[J].Journal of Power Sources, 2015, 282:299-322 [5] Ying Zhang, Ke Ye, Kui Cheng, et al.Three-dimensional lamination-like P2-Na2/3Ni1/3Mn2/3O2 assembled with two-dimensional ultrathin nanosheets as the cathode material of an aqueous capacitor batteryOriginal Research Article [J].Electrochimica Acta, 2014, 148:195-202.[J].Electrochimica Acta, 2014, 148:195-202 [6]徐玲荣,孙建红,叶琴.锂离子电池正极材料的研究与应用现状探究[J].化学工程与装备, 2012, (1):105-105 [7]Xianhua Hou,Yangling Huang, Shaomeng Ma, et al.Facile hydrothermal method synthesis of coralline-like Li1.2Mn0.54Ni0.13Co0.13O2 hierarchical architectures as superior cathode materials for lithium-ion batteries [J].Materials Research Bulletin, ,2015, 63:256-264 [8]黄果, 杨顺毅,雷钢铁,等.十正极材料的喷雾干燥法合成及电化学性能[J].中国有色金属学报, 2014, 24(3):725-732 [9]Xianhua Hou, Xiaoli Zou, Yanling Huang, et al.Surfactant CTAB-assisted synthesis of Li113[Ni0.233Mn0.534Co0.233]0.87O2 with festoon-like hierarchical architectures as cathode materials for Li-ion batteries with outstanding performance[J].RSC Advances, 2014, 4(56):29534-29541 [10]Chenhao Zhao, Qiang Shen.Organic acid assisted solid-state synthesis of Li12Ni0.16Co0.08Mn0.56O2 nanoparticles as lithium ion battery cathodesOriginal Research Article[J].Current Applied Physics, 2014, 14(12):1849-1853 [11] Shoaib Muhammad, Sangwoo Lee, Hyunchul Kim, et al.Deciphering the thermal behavior of lithium rich cathode material by in situ X-ray diffraction techniqueOriginal Research Article [J].Journal of Power Sources, 2015, 285:56-160 [12]Jan Geder, Jay Hyok Song, Sun Ho Kang, et al.Thermal stability of lithium-rich manganese-based cathode Original Research Article[J].Solid State Ionics, 2014, 268(Part B):242-246 [13] Fan Yang, Qinggang Zhang, Xiaohong Hu, et al.Synthesis of layered xLi2MnO3?(1 ? x)LiMnO2 nanoplates and its electrochemical performance as Li-rich cathode materials for Li-ion batteryOriginal Research Article[J].Electrochimica Acta, 2015, 165:182-190 [14] Jingwen Zhang, Xun Guo, Sumei Yao, Wentao Zhu, et al.Tailored synthesis of Ni0.25Mn0.75CO3 spherical precursors for high capacity Li-rich cathode materials via a urea-based precipitation method[J].Journal of Power Sources, 2013, 238:245-250 [15] Xiukang Yang, Xianyou Wang, Guishan Zou, et al.Spherical lithium-rich layered Li1.13[Mn0.534Ni0.233Co0.233]0.87O2 with concentration-gradient outer layer as high-performance cathodes for lithium ion batteriesOriginal Research Article[J].Journal of Power Sources, 2013, 232:338-347 [16]Jae-Won Lee, Doosung Hwang.Application of thermodynamic activity models to the equilibrium potential for lithium intercalation process of a cobalt-free cathode material with a layered structureOriginal Research Article[J].Computational Materials Science, 2015, 100(Part A):80-83 [17] Jun Wang, Bao Qiu, Hailiang Cao, et al.Electrochemical properties of 0.6Li[Li1/3Mn2/3]O2–0.4LiNixMnyCo1?x?yO2 cathode materials for lithium-ion batteriesOriginal Research Article[J].Journal of Power Sources, 2012, 218:128-133 [18]Chenhao Zhao, Qiang Shen.Organic acid assisted solid-state synthesis of Li12Ni0.16Co0.08Mn0.56O2 nanoparticles as lithium ion battery cathodesOriginal Research Article[J].Current Applied Physics, 2014, 14(12):1849-1853 [19]J.M. Zheng,XB. Wu,Y. Yang.A comparison of preparation method on the electrochemical performance of cathode material Li[Li0.2Mn0.54Ni0.13Co0.13]O2 for lithium ion battery Original Research Article[J].Electrochimica Acta, 2011, 56(8):3071-3078 [20]Ho-Hyun Sun, Wonchang Choi, Joong Kee Lee, et al.Control of electrochemical properties of nickel-rich layered cathode materials for lithium ion batteries by variation of the manganese to cobalt ratioOriginal Research Article[J].Journal of Power Sources, 2015, 275: 877-883
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出版历程
  • 收稿日期:  2015-05-31
  • 修回日期:  2015-06-22
  • 刊出日期:  2015-11-25

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