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氨基化MCM-41介孔分子筛改性超滤膜去除水中Cr(VI)的研究

晏晓敏 包一翔 谢小妮 周佳璐 李来胜

晏晓敏, 包一翔, 谢小妮, 周佳璐, 李来胜. 氨基化MCM-41介孔分子筛改性超滤膜去除水中Cr(VI)的研究[J]. 华南师范大学学报(自然科学版), 2015, 47(6): 58-62.
引用本文: 晏晓敏, 包一翔, 谢小妮, 周佳璐, 李来胜. 氨基化MCM-41介孔分子筛改性超滤膜去除水中Cr(VI)的研究[J]. 华南师范大学学报(自然科学版), 2015, 47(6): 58-62.
REMOVAL OF Cr (VI) FROM AQUEOUS SOLUTION BY AMINE-FUNCTIONALIZED MCM-41 MODIFIED ULTRAFILTRATION MEMBRANE[J]. Journal of South China normal University (Natural Science Edition), 2015, 47(6): 58-62.
Citation: REMOVAL OF Cr (VI) FROM AQUEOUS SOLUTION BY AMINE-FUNCTIONALIZED MCM-41 MODIFIED ULTRAFILTRATION MEMBRANE[J]. Journal of South China normal University (Natural Science Edition), 2015, 47(6): 58-62.

氨基化MCM-41介孔分子筛改性超滤膜去除水中Cr(VI)的研究

基金项目: 

国家十二五重大水专项

详细信息
    通讯作者:

    晏晓敏

  • 中图分类号: X5

REMOVAL OF Cr (VI) FROM AQUEOUS SOLUTION BY AMINE-FUNCTIONALIZED MCM-41 MODIFIED ULTRAFILTRATION MEMBRANE

  • 摘要: 采用氨基化MCM-41介孔分子筛(NH2-MCM-41)接枝改性聚偏氟乙烯(PVDF)超滤膜,并用于水中重金属Cr(VI)的去除。NH2-MCM-41成功接枝于超滤膜表面,并在表面形成均匀的亲水层,显著提高了膜的抗污染性能,过水通量衰减率从51.4%降低到了24.8%。在pH值3.5,初始浓度20 mg/L时,改性超滤膜对Cr(VI)的吸附可以在5 min达到快速平衡,吸附容量达到2.8 mg/g。超滤实验表明,NH2-MCM-41改性超滤膜对低浓度Cr(VI)进水可以实现进一步净化,在超滤运行时长达到11 h,出水Cr(VI)浓度始终维持在0.5 mg/L以下。因此,本研究通过在膜表面接枝氨基化的MCM-41分子筛,可以有效提升膜的抗污染能力和对重金属的去除能力。
  • [1] Weiquan Cai, Lijun Tan, Jiaguo Yu, MietekJaroniec, Xiaoqin Liu, Bei Cheng, Francis Verpoort. Synthesis of amino-functionalized mesoporous alumina with enhanced affinity towards Cr (VI) and CO2[J]. Chemical Engineering Journal, 2014, 239:207-215
    [2] LY Li, H Cui, JR Grace. Exploration of remediation of acid rock drainage with clinoptilolite as sorbent in a slurry bubble column for both heavy metal capture and regeneration [J]. Water Research, 2006,40:3359–3366.
    [3] O Abollino, Giacomino A, Malandrino M, Mentasti E. Interaction of metal ions with montmorillonite and vermiculite [J]. Applied Clay Science, 2008,38:227-236
    [4] Julin Cao, Yunhai Wu, Yanping Jin, Palizhati Yilihan, Wenfu Huang. Response surface methodology approach for optimization of the removal of chromium (VI) by NH2-MCM-41 [J]. Journal of the Taiwan Institute of Chemical Engineers,2014, 45:860-868
    [5] Aghdas Heidari, Habibollah Younesi, Zahra Mehraban. Removal of Ni (II), Cd (II), and Pb (II) from a ternary aqueous solution by amino functionalized mesoporous and nano mesoporous silica [J].Chemical Engineering Journal, 2009,153 :70-79
    [6] M Shariaty-Niassar A Ghaee, J Barzin, T Matsuura. Effects of chitosan membrane morphology on copper ion adsorption [J]. Chemical Engineering Journal, 2010,165:46-55
    [7] E Salehi, S S Madaeni, L Rajabi, V Vatanpour, A A Derakhshan, S Zinadini, S Ghorabi, H Ahmadi Monfared. Novel chitosan/poly(vinyl) alcohol thin adsorptive membranes modified with amino functionalized multi-walled carbon nanotubes for Cu (II) removal from water: Preparation, characterization, adsorption kinetics and thermodynamics [J]. Separation and Purification Technology,2012,89 :309-319
    [8] R Jamshidi Gohari, W J Lau, T Matsuur, E Halakoo, A F Ismail. Adsorptive removal of Pb (II) from aqueous solution by novel PES/HMO ultrafiltration mixed matrix membrane [J]. Separation and Purification Technology, 2013,120:59–68
    [9] Y Shao, X Wang, Y Kang, Y Shu, Q Sun, L Li. Application of Mn/MCM-41 as an adsorbent to remove methyl blue from aqueous solution [J]. Journal of Colloid Interface Science, 2014,429:25-33
    [10] Yunhai Wu, Yanping Jin, Julin Cao,Palizhati Yilihan, Yajun Wen, Jianxin Zhou. Optimizing adsorption of arsenic (III)by NH2-MCM-41 using response surface methodology [J]. Journal of Industrial and Engineering Chemistry, 2014,20:1285-1292
    [11] Jun Yin, Eun-Sik Kim, John Yang, Baolin Deng. Fabrication of a novel thin-film nanocomposite (TFN) membrane containing MCM-41 silica nanoparticles (NPs) for water purification [J]. Journal of Membrane Science, 2012,423-424 :238-246
    [12] D Rana B J A Tarboush, T Matsuura, H A Arafat, R M Narbaitz. Preparation of thin-film-composite polyamide membranes for desalination using novel hydrophilic surface modifying macromolecules [J]. Journal of Membrane Science, 2008,325 :166-175
    [13] Julin Cao,Yunhai Wu, Yanping Jin, PalizhatiYilihan, Wenfu Huang. Response surface methodology approach for optimization of the removal of chromium(VI) by NH2-MCM-41 [J]. Journal of the Taiwan Institute of Chemical Engineers, 2014,45:860-868
    [14] Kulamani Parida, Krushna Gopal Mishra, Suresh Kumar Dash. Adsorption of toxic metal ion Cr (VI) from aqueous state by TiO2-MCM-41:Equilibrium and kinetic studies [J]. Journal of Hazardous Materials, 2012,241-242 : 395–403
    [15] Hu Tang, Chunyu Chang, Lina Zhang. Efficient adsorption of Hg2+ ions on chitin/cellulose composite membranes prepared via environmentally friendly pathway [J]. Chemical Engineering Journal, 2011,173:689-697
    [16] Ye Tian, Min Wu, Ruigang Liu, Yanxiang Li, Deqian Wang, Junjun Tan, Rongcheng Wu, Yong Huang. Electrospun membrane of cellulose acetate for heavy metal ion adsorption in water treatment [J]. Carbohydrate Polymers,2011, 83:743-748
    [17] Mohamed Mahmoud Nasef, Abdul Hamid Yahaya. Adsorption of some heavy metal ions from aqueous solutions on Nafion 117 membrane [J]. Desalination, 2009,249:677-681
    [18] RajangamVinodh, Rajangam Padmavathi, Dharmalingam Sangeetha. Separation of heavy metals from water samples using anion exchange polymers by adsorption process [J]. Desalination, 2011,267 : 267-276

    [1] Weiquan Cai, Lijun Tan, Jiaguo Yu, MietekJaroniec, Xiaoqin Liu, Bei Cheng, Francis Verpoort. Synthesis of amino-functionalized mesoporous alumina with enhanced affinity towards Cr (VI) and CO2[J]. Chemical Engineering Journal, 2014, 239:207-215
    [2] LY Li, H Cui, JR Grace. Exploration of remediation of acid rock drainage with clinoptilolite as sorbent in a slurry bubble column for both heavy metal capture and regeneration [J]. Water Research, 2006,40:3359–3366.
    [3] O Abollino, Giacomino A, Malandrino M, Mentasti E. Interaction of metal ions with montmorillonite and vermiculite [J]. Applied Clay Science, 2008,38:227-236
    [4] Julin Cao, Yunhai Wu, Yanping Jin, Palizhati Yilihan, Wenfu Huang. Response surface methodology approach for optimization of the removal of chromium (VI) by NH2-MCM-41 [J]. Journal of the Taiwan Institute of Chemical Engineers,2014, 45:860-868
    [5] Aghdas Heidari, Habibollah Younesi, Zahra Mehraban. Removal of Ni (II), Cd (II), and Pb (II) from a ternary aqueous solution by amino functionalized mesoporous and nano mesoporous silica [J].Chemical Engineering Journal, 2009,153 :70-79
    [6] M Shariaty-Niassar A Ghaee, J Barzin, T Matsuura. Effects of chitosan membrane morphology on copper ion adsorption [J]. Chemical Engineering Journal, 2010,165:46-55
    [7] E Salehi, S S Madaeni, L Rajabi, V Vatanpour, A A Derakhshan, S Zinadini, S Ghorabi, H Ahmadi Monfared. Novel chitosan/poly(vinyl) alcohol thin adsorptive membranes modified with amino functionalized multi-walled carbon nanotubes for Cu (II) removal from water: Preparation, characterization, adsorption kinetics and thermodynamics [J]. Separation and Purification Technology,2012,89 :309-319
    [8] R Jamshidi Gohari, W J Lau, T Matsuur, E Halakoo, A F Ismail. Adsorptive removal of Pb (II) from aqueous solution by novel PES/HMO ultrafiltration mixed matrix membrane [J]. Separation and Purification Technology, 2013,120:59–68
    [9] Y Shao, X Wang, Y Kang, Y Shu, Q Sun, L Li. Application of Mn/MCM-41 as an adsorbent to remove methyl blue from aqueous solution [J]. Journal of Colloid Interface Science, 2014,429:25-33
    [10] Yunhai Wu, Yanping Jin, Julin Cao,Palizhati Yilihan, Yajun Wen, Jianxin Zhou. Optimizing adsorption of arsenic (III)by NH2-MCM-41 using response surface methodology [J]. Journal of Industrial and Engineering Chemistry, 2014,20:1285-1292
    [11] Jun Yin, Eun-Sik Kim, John Yang, Baolin Deng. Fabrication of a novel thin-film nanocomposite (TFN) membrane containing MCM-41 silica nanoparticles (NPs) for water purification [J]. Journal of Membrane Science, 2012,423-424 :238-246
    [12] D Rana B J A Tarboush, T Matsuura, H A Arafat, R M Narbaitz. Preparation of thin-film-composite polyamide membranes for desalination using novel hydrophilic surface modifying macromolecules [J]. Journal of Membrane Science, 2008,325 :166-175
    [13] Julin Cao,Yunhai Wu, Yanping Jin, PalizhatiYilihan, Wenfu Huang. Response surface methodology approach for optimization of the removal of chromium(VI) by NH2-MCM-41 [J]. Journal of the Taiwan Institute of Chemical Engineers, 2014,45:860-868
    [14] Kulamani Parida, Krushna Gopal Mishra, Suresh Kumar Dash. Adsorption of toxic metal ion Cr (VI) from aqueous state by TiO2-MCM-41:Equilibrium and kinetic studies [J]. Journal of Hazardous Materials, 2012,241-242 : 395–403
    [15] Hu Tang, Chunyu Chang, Lina Zhang. Efficient adsorption of Hg2+ ions on chitin/cellulose composite membranes prepared via environmentally friendly pathway [J]. Chemical Engineering Journal, 2011,173:689-697
    [16] Ye Tian, Min Wu, Ruigang Liu, Yanxiang Li, Deqian Wang, Junjun Tan, Rongcheng Wu, Yong Huang. Electrospun membrane of cellulose acetate for heavy metal ion adsorption in water treatment [J]. Carbohydrate Polymers,2011, 83:743-748
    [17] Mohamed Mahmoud Nasef, Abdul Hamid Yahaya. Adsorption of some heavy metal ions from aqueous solutions on Nafion 117 membrane [J]. Desalination, 2009,249:677-681
    [18] RajangamVinodh, Rajangam Padmavathi, Dharmalingam Sangeetha. Separation of heavy metals from water samples using anion exchange polymers by adsorption process [J]. Desalination, 2011,267 : 267-276
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出版历程
  • 收稿日期:  2015-03-06
  • 修回日期:  2015-03-30
  • 刊出日期:  2015-11-25

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