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3-吡啶甲酰基丙酮酸乙酯铜配合物的合成和结构研究

龙晓君 姚悦 温美凤 吴建中

龙晓君, 姚悦, 温美凤, 吴建中. 3-吡啶甲酰基丙酮酸乙酯铜配合物的合成和结构研究[J]. 华南师范大学学报(自然科学版), 2015, 47(6): 48-51.
引用本文: 龙晓君, 姚悦, 温美凤, 吴建中. 3-吡啶甲酰基丙酮酸乙酯铜配合物的合成和结构研究[J]. 华南师范大学学报(自然科学版), 2015, 47(6): 48-51.
Synthesis and Structural Studies of a Cu(II) Complex with 3-pyridylformylpyruvic Acid Ethyl Ester[J]. Journal of South China normal University (Natural Science Edition), 2015, 47(6): 48-51.
Citation: Synthesis and Structural Studies of a Cu(II) Complex with 3-pyridylformylpyruvic Acid Ethyl Ester[J]. Journal of South China normal University (Natural Science Edition), 2015, 47(6): 48-51.

3-吡啶甲酰基丙酮酸乙酯铜配合物的合成和结构研究

基金项目: 

项目编号:2013B090500123,项目名称: 新型微纳米光纤传感技术研究及其在大气环境检测与评估中的应用

详细信息
    通讯作者:

    吴建中

Synthesis and Structural Studies of a Cu(II) Complex with 3-pyridylformylpyruvic Acid Ethyl Ester

Funds: 

广东省科技计划项目2013B090500123

  • 摘要: 以3-乙酰基吡啶和草酸二乙酯为原料,合成得到3-吡啶甲酰基丙酮酸乙酯(简称HL),核磁共振波谱表明该物质的?-二酮部分在溶液中采取烯醇式结构。通过界面扩散法合成了该配体的第一个配合物{CuL2}n,并用单晶X-射线衍射进行了详细的结构分析。该配位聚合物中Cu(II)与四个L?配体形成拉长的反式CuN2(OO)2八面体配位构型。两种晶体学独立的L?配体都是以?-二酮基的两个O原子螯合一个Cu(II), 以吡啶N原子与另一个Cu(II)配位,形成二维网格结构。
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    [2] Coronado E, Minguez Espallargas G. Dynamic magnetic MOFs [J]. Chemical Society Reviews, 2013, 42 (4): 1525-39.
    [3] Cui Y, Yue Y, Qian G, et al. Luminescent Functional Metal–Organic Frameworks [J]. Chemical Reviews, 2011, 112 (2): 1126-62.
    [4] Czaja A U, Trukhan N, Muller U. Industrial applications of metal-organic frameworks [J]. Chemical Society Reviews, 2009, 38 (5): 1284-93.
    [5] Li J-R, Kuppler R J, Zhou H-C. Selective gas adsorption and separation in metal-organic frameworks [J]. Chemical Society Reviews, 2009, 38 (5): 1477-504.
    [6] Rocha J, Carlos L D, Paz F a A, et al. Luminescent multifunctional lanthanides-based metal-organic frameworks [J]. Chemical Society Reviews, 2011, 40 (2): 926-40.
    [7] Xuan W, Zhu C, Liu Y, et al. Mesoporous metal-organic framework materials [J]. Chemical Society Reviews, 2012, 41 (5): 1677-95.
    [8] Liu L-F, Cai B, He C-S, et al. Coordination and topology versatility of metal-organic frameworks based on cadmium iodide and 5-azaarylpyrazole-3-carboxylic acids [J]. Inorganic Chemistry Communications, 2013, 30 (1): 105-10.
    [9] Li X-Z, He J-H, Liao D-Z. Synthesis and structure of a Ni(II)-Cu(II)-Ni(II) trinuclear complex with a new macrocyclic complex ligand [J]. Acta Chim. Slov., 2005, 52 (3): 332-5.
    [10] Prout K, Mtetwa V S B, Rossotti F J C. Structure and stability of carboxylate complexes. XIX. The structures of diamminebis(glycolato)copper(II), tetraamminebis(ethoxyacetato)copper(II), bis(glycolato)bis(pyridine)copper(II) and bis(ethoxyacetato)bis(pyridine)copper(II) [J]. Acta Crystallography, 1993, B49 (1): 73-9.
    [11] Zhang L, Zhao S-J, Zhu L-N, et al. A trigonal-prismatic Ag(I) complex and an octahedral Cu(II) complex incorporating with oxamide Ni(II) complex ligand: Syntheses, crystal structures and oxidative nuclease activities [J]. Inorg. Chim. Acta, 2011, 375 (1): 135-41.
    [12] Keene T D, Hursthouse M B, Price D J. trans-bis(2-Aminoanilinium-N)-bis(oxalato-O,O')-copper(II) [J]. Acta Crystallography, 2003, E59 (12): m1131-3.
    [13] Okabe N, Yamamoto E, Yasunori M. Trans-Bis(3-hydroxy-2-phenyl-4H-1-benzopyran-4-onato)bis(pyridine)copper(II) [J]. Acta Crystallography, 2003, E59 (9): m715-6.

    [1] Almeida Paz F A, Klinowski J, Vilela S M F, et al. Ligand design for functional metal-organic frameworks [J]. Chemical Society Reviews, 2012, 41 (3): 1088-110.
    [2] Coronado E, Minguez Espallargas G. Dynamic magnetic MOFs [J]. Chemical Society Reviews, 2013, 42 (4): 1525-39.
    [3] Cui Y, Yue Y, Qian G, et al. Luminescent Functional Metal–Organic Frameworks [J]. Chemical Reviews, 2011, 112 (2): 1126-62.
    [4] Czaja A U, Trukhan N, Muller U. Industrial applications of metal-organic frameworks [J]. Chemical Society Reviews, 2009, 38 (5): 1284-93.
    [5] Li J-R, Kuppler R J, Zhou H-C. Selective gas adsorption and separation in metal-organic frameworks [J]. Chemical Society Reviews, 2009, 38 (5): 1477-504.
    [6] Rocha J, Carlos L D, Paz F a A, et al. Luminescent multifunctional lanthanides-based metal-organic frameworks [J]. Chemical Society Reviews, 2011, 40 (2): 926-40.
    [7] Xuan W, Zhu C, Liu Y, et al. Mesoporous metal-organic framework materials [J]. Chemical Society Reviews, 2012, 41 (5): 1677-95.
    [8] Liu L-F, Cai B, He C-S, et al. Coordination and topology versatility of metal-organic frameworks based on cadmium iodide and 5-azaarylpyrazole-3-carboxylic acids [J]. Inorganic Chemistry Communications, 2013, 30 (1): 105-10.
    [9] Li X-Z, He J-H, Liao D-Z. Synthesis and structure of a Ni(II)-Cu(II)-Ni(II) trinuclear complex with a new macrocyclic complex ligand [J]. Acta Chim. Slov., 2005, 52 (3): 332-5.
    [10] Prout K, Mtetwa V S B, Rossotti F J C. Structure and stability of carboxylate complexes. XIX. The structures of diamminebis(glycolato)copper(II), tetraamminebis(ethoxyacetato)copper(II), bis(glycolato)bis(pyridine)copper(II) and bis(ethoxyacetato)bis(pyridine)copper(II) [J]. Acta Crystallography, 1993, B49 (1): 73-9.
    [11] Zhang L, Zhao S-J, Zhu L-N, et al. A trigonal-prismatic Ag(I) complex and an octahedral Cu(II) complex incorporating with oxamide Ni(II) complex ligand: Syntheses, crystal structures and oxidative nuclease activities [J]. Inorg. Chim. Acta, 2011, 375 (1): 135-41.
    [12] Keene T D, Hursthouse M B, Price D J. trans-bis(2-Aminoanilinium-N)-bis(oxalato-O,O')-copper(II) [J]. Acta Crystallography, 2003, E59 (12): m1131-3.
    [13] Okabe N, Yamamoto E, Yasunori M. Trans-Bis(3-hydroxy-2-phenyl-4H-1-benzopyran-4-onato)bis(pyridine)copper(II) [J]. Acta Crystallography, 2003, E59 (9): m715-6.
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出版历程
  • 收稿日期:  2015-03-04
  • 修回日期:  2015-03-08
  • 刊出日期:  2015-11-25

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