多孔Ti3C2Tx/SnSe复合材料的制备及其储钾性能

The Synthesis of Porous Ti3C2Tx/SnSe Composite and Its Potassium Storage Performance

  • 摘要: 采用原位氧化-刻蚀法和水热合成法制备了多孔MXene复合材料(Ti3C2Tx/SnSe),并对所制备的材料进行了结构表征与电化学性能测试. 结果表明:在0.05 A/g的电流密度下,多孔Ti3C2Tx/SnSe电极具有381.9 mA ·h/g的储钾容量,而相同情况下SnSe电极的比容量仅为119.2 mA ·h/g. 在1 A/g的电流密度下,多孔Ti3C2Tx /SnSe电极的初始可逆比容量为118.5 mA ·h/g,循环500次的比容量仍保持在35.4 mA ·h/g. 多孔Ti3C2Tx/SnSe电极材料优异的电化学性能得益于多孔Ti3C2Tx材料的高导电性,它不仅缓解了SnSe的体积膨胀,而且为离子的转移提供了良好的通路.

     

    Abstract: The porous MXene composite material (Ti3C2Tx/SnSe) was fabricated with the in-situ oxidation-etching method and the hydrothermal synthesis technology. The composition, structure and electrochemical properties of the prepared materials were evaluated. The research results showed that the porous Ti3C2Tx/SnSe electrode deliveed a capacity of 381.5 mA ·h/g at a current density of 0.05 A/g while the specific capacity of the pure SnSe electrode was only 119.2 mA ·h/g. At a current density of 1 A/g, the Ti3C2Tx/SnSe electrode showed an initial reversible specific capacity of 118.5 mA ·h/g and it remained at 35.4 mA ·h/g after 500 cycles. The excellent electrochemical performance of the porous Ti3C2Tx/SnSe electrode material mainly benefits from the high conductivity of Ti3C2Tx, which not only alleviates the volume expansion of SnSe but also provides a good path for the ionic transfer.

     

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